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Atoms and Molecules - Properties of the Ionic and the Covalent

Grade 9CBSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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Ionic compounds are formed by the transfer of electrons from a metal to a non-metal, resulting in the formation of cations (e.g., Na+Na^+) and anions (e.g., Cl−Cl^-).

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Ionic compounds have high melting and boiling points because a large amount of energy is required to break the strong electrostatic forces of attraction between the oppositely charged ions.

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Ionic compounds are generally soluble in water but insoluble in organic solvents like kerosene or petrol. They conduct electricity in molten or aqueous states due to the movement of free ions, but not in the solid state.

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Covalent compounds are formed by the sharing of one or more pairs of electrons between two atoms, typically non-metals (e.g., H2OH_2O, CH4CH_4).

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Covalent compounds generally have low melting and boiling points because the intermolecular forces (Van der Waals forces) between the molecules are weak.

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Covalent compounds are mostly poor conductors of electricity because they do not form ions in solution and consist of neutral molecules.

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The chemical formula of a compound is determined by the valencies of the constituent elements. For example, to form Magnesium Chloride, MgMg has a valency of 2+2+ and ClCl has a valency of 1−1-, resulting in MgCl2MgCl_2.

📐Formulae

Ionic Bond Formation: M→Mn++ne− and X+me−→Xm−\text{Ionic Bond Formation: } M \rightarrow M^{n+} + ne^- \text{ and } X + me^- \rightarrow X^{m-}

Aluminum Oxide: Al3++O2−→Al2O3\text{Aluminum Oxide: } Al^{3+} + O^{2-} \rightarrow Al_2O_3

Calcium Carbonate: Ca2++CO32−→CaCO3\text{Calcium Carbonate: } Ca^{2+} + CO_3^{2-} \rightarrow CaCO_3

Methane (Covalent): C+4H→CH4\text{Methane (Covalent): } C + 4H \rightarrow CH_4

💡Examples

Problem 1:

Explain why Sodium Chloride (NaClNaCl) has a high melting point (1081K1081 K) while Carbon Tetrachloride (CCl4CCl_4) has a low melting point (250K250 K).

Solution:

NaClNaCl is an ionic compound, whereas CCl4CCl_4 is a covalent compound.

Explanation:

In NaClNaCl, the constituent particles are Na+Na^+ and Cl−Cl^- ions held together by very strong electrostatic forces of attraction, requiring significant thermal energy to overcome. In CCl4CCl_4, the atoms are held by covalent bonds, and the molecules are held together by weak intermolecular forces which are easily broken at lower temperatures.

Problem 2:

Write the chemical formula for Aluminum Sulphate.

Solution:

Al2(SO4)3Al_2(SO_4)_3

Explanation:

Aluminum has a valency of 3+3+ (Al3+Al^{3+}) and the Sulphate polyatomic ion has a valency of 2−2- (SO42−SO_4^{2-}). By crossing over the valencies: AlAl gets 22 and SO4SO_4 gets 33. Thus, the formula is Al2(SO4)3Al_2(SO_4)_3.

Problem 3:

Does a solution of Glucose (C6H12O6C_6H_{12}O_6) conduct electricity? Why or why not?

Solution:

No, it does not conduct electricity.

Explanation:

Glucose is a covalent compound. When dissolved in water, it does not dissociate into ions. Since there are no free-moving ions or electrons to carry the electric charge, the solution remains non-conductive.

Properties of the Ionic and the Covalent Class 9 Notes & Examples