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Atoms and Molecules - Dalton’s Atomic Theory

Grade 9CBSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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Dalton’s Atomic Theory provides an explanation for the Law of Conservation of Mass and the Law of Definite Proportions.

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All matter is made of very tiny particles called atoms, which participate in chemical reactions.

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Atoms are indivisible particles, which cannot be created or destroyed in a chemical reaction. This aligns with the Law of Conservation of Mass: Massreactants=MassproductsMass_{reactants} = Mass_{products}.

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Atoms of a given element are identical in mass and chemical properties, whereas atoms of different elements have different masses and chemical properties.

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Atoms combine in the ratio of small whole numbers to form compounds. For example, in water (H2OH_2O), the ratio of the mass of hydrogen to the mass of oxygen is always 1:81:8.

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The relative number and kinds of atoms are constant in a given compound, supporting the Law of Constant Proportions.

📐Formulae

Total Mass of Reactants=Total Mass of ProductsTotal\ Mass\ of\ Reactants = Total\ Mass\ of\ Products

Mass Ratio in H2O⇒H:O=1:8\text{Mass Ratio in } H_2O \Rightarrow H:O = 1:8

Mass Ratio in NH3⇒N:H=14:3\text{Mass Ratio in } NH_3 \Rightarrow N:H = 14:3

Number of Atoms∝Mass (for a specific element)\text{Number of Atoms} \propto \text{Mass (for a specific element)}

💡Examples

Problem 1:

In a reaction, 5.3 g5.3\text{ g} of sodium carbonate reacted with 6.0 g6.0\text{ g} of ethanoic acid. The products were 8.2 g8.2\text{ g} of sodium ethanoate, 2.2 g2.2\text{ g} of CO2CO_2 and 0.9 g0.9\text{ g} of H2OH_2O. Show that these observations are in agreement with the law of conservation of mass.

Solution:

Mass of reactants: 5.3 g+6.0 g=11.3 g5.3\text{ g} + 6.0\text{ g} = 11.3\text{ g}. Mass of products: 8.2 g+2.2 g+0.9 g=11.3 g8.2\text{ g} + 2.2\text{ g} + 0.9\text{ g} = 11.3\text{ g}. Since 11.3 g=11.3 g11.3\text{ g} = 11.3\text{ g}, the law is verified.

Explanation:

According to the Law of Conservation of Mass, the total mass before and after a chemical reaction must be equal. Calculation of reactants: 5.3+6.011.3\begin{array}{r} 5.3 \\ + 6.0 \\ \hline 11.3 \end{array} Calculation of products: 8.22.2+0.911.3\begin{array}{r} 8.2 \\ 2.2 \\ + 0.9 \\ \hline 11.3 \end{array}

Problem 2:

Hydrogen and oxygen combine in the ratio of 1:81:8 by mass to form water. What mass of oxygen gas would be required to react completely with 3 g3\text{ g} of hydrogen gas?

Solution:

Mass of oxygen = 3×8=24 g3 \times 8 = 24\text{ g}.

Explanation:

Dalton's theory states atoms combine in fixed ratios. Given the ratio of H:OH:O is 1:81:8: Mass of HMass of O=18\frac{\text{Mass of H}}{\text{Mass of O}} = \frac{1}{8} 3 gMass of O=18\frac{3\text{ g}}{\text{Mass of O}} = \frac{1}{8} Mass of O=3×8=24 g\text{Mass of O} = 3 \times 8 = 24\text{ g}

Dalton’s Atomic Theory Class 9 Notes & Examples