Review the key concepts, formulae, and examples before starting your quiz.
🔑Concepts
The Law of Constant Proportions was stated by Joseph Proust in 1799.
It states: 'In a chemical substance, the elements are always present in definite proportions by mass.'
This law is also known as the Law of Definite Proportions.
The law implies that no matter the source or the method of preparation, a pure chemical compound always contains the same elements combined together in the same fixed ratio by mass.
For example, in water (), the ratio of the mass of hydrogen to the mass of oxygen is always , regardless of the source of water.
In ammonia (), nitrogen and hydrogen are always present in the ratio by mass.
📐Formulae
💡Examples
Problem 1:
of hydrogen gas reacts with of oxygen gas to form water. What mass of oxygen gas would be required to react completely with of hydrogen gas?
Solution:
According to the Law of Constant Proportions, hydrogen and oxygen always react in a fixed ratio of by mass to form water.
Given:
To find the oxygen required for of hydrogen:
Explanation:
Since the ratio of is constant at , if we triple the amount of hydrogen from to , the required oxygen must also be tripled () or calculated via the fixed ratio.
Problem 2:
In an experiment, of Phosphorus reacted with Oxygen to form of Phosphorus oxide. In another experiment, of Phosphorus gave of the same oxide. Show that these results follow the Law of Constant Proportions.
Solution:
In Experiment 1:
In Experiment 2:
Since the ratio is the same (), the law is verified.
Explanation:
The ratio of the masses of the constituent elements (Phosphorus and Oxygen) remains constant across different experiments for the same compound.