krit.club logo

Atoms and Molecules - Law of Constant Proportions

Grade 9CBSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

•

The Law of Constant Proportions was stated by Joseph Proust in 1799.

•

It states: 'In a chemical substance, the elements are always present in definite proportions by mass.'

•

This law is also known as the Law of Definite Proportions.

•

The law implies that no matter the source or the method of preparation, a pure chemical compound always contains the same elements combined together in the same fixed ratio by mass.

•

For example, in water (H2OH_2O), the ratio of the mass of hydrogen to the mass of oxygen is always 1:81:8, regardless of the source of water.

•

In ammonia (NH3NH_3), nitrogen and hydrogen are always present in the ratio 14:314:3 by mass.

📐Formulae

Ratio by Mass=Mass of Element AMass of Element B=Constant\text{Ratio by Mass} = \frac{\text{Mass of Element A}}{\text{Mass of Element B}} = \text{Constant}

Mass ratio in H2O⇒Hydrogen:Oxygen=1:8\text{Mass ratio in } H_2O \Rightarrow \text{Hydrogen} : \text{Oxygen} = 1 : 8

Mass ratio in NH3⇒Nitrogen:Hydrogen=14:3\text{Mass ratio in } NH_3 \Rightarrow \text{Nitrogen} : \text{Hydrogen} = 14 : 3

Mass ratio in CO2⇒Carbon:Oxygen=3:8\text{Mass ratio in } CO_2 \Rightarrow \text{Carbon} : \text{Oxygen} = 3 : 8

💡Examples

Problem 1:

3.0 g3.0 \text{ g} of hydrogen gas reacts with 24.0 g24.0 \text{ g} of oxygen gas to form water. What mass of oxygen gas would be required to react completely with 9.0 g9.0 \text{ g} of hydrogen gas?

Solution:

According to the Law of Constant Proportions, hydrogen and oxygen always react in a fixed ratio of 1:81:8 by mass to form water.

Given: Mass of Hydrogen=3.0 g\text{Mass of Hydrogen} = 3.0 \text{ g} Mass of Oxygen=24.0 g\text{Mass of Oxygen} = 24.0 \text{ g} Ratio=3.024.0=18\text{Ratio} = \frac{3.0}{24.0} = \frac{1}{8}

To find the oxygen required for 9.0 g9.0 \text{ g} of hydrogen: Mass of HydrogenMass of Oxygen=18\frac{\text{Mass of Hydrogen}}{\text{Mass of Oxygen}} = \frac{1}{8} 9.0Mass of Oxygen=18\frac{9.0}{\text{Mass of Oxygen}} = \frac{1}{8} Mass of Oxygen=9.0×8=72.0 g\text{Mass of Oxygen} = 9.0 \times 8 = 72.0 \text{ g}

Explanation:

Since the ratio of H:OH:O is constant at 1:81:8, if we triple the amount of hydrogen from 3 g3\text{ g} to 9 g9\text{ g}, the required oxygen must also be tripled (24×324 \times 3) or calculated via the fixed ratio.

Problem 2:

In an experiment, 1.24 g1.24 \text{ g} of Phosphorus reacted with Oxygen to form 2.84 g2.84 \text{ g} of Phosphorus oxide. In another experiment, 2.48 g2.48 \text{ g} of Phosphorus gave 5.68 g5.68 \text{ g} of the same oxide. Show that these results follow the Law of Constant Proportions.

Solution:

In Experiment 1: Mass of P=1.24 g\text{Mass of P} = 1.24 \text{ g} Mass of Oxide=2.84 g\text{Mass of Oxide} = 2.84 \text{ g} Mass of O=2.84−1.24=1.60 g\text{Mass of O} = 2.84 - 1.24 = 1.60 \text{ g} Ratio of P:O=1.241.60=0.775\text{Ratio of P:O} = \frac{1.24}{1.60} = 0.775

In Experiment 2: Mass of P=2.48 g\text{Mass of P} = 2.48 \text{ g} Mass of Oxide=5.68 g\text{Mass of Oxide} = 5.68 \text{ g} Mass of O=5.68−2.48=3.20 g\text{Mass of O} = 5.68 - 2.48 = 3.20 \text{ g} Ratio of P:O=2.483.20=0.775\text{Ratio of P:O} = \frac{2.48}{3.20} = 0.775

Since the ratio is the same (0.775:10.775:1), the law is verified.

Explanation:

The ratio of the masses of the constituent elements (Phosphorus and Oxygen) remains constant across different experiments for the same compound.

Law of Constant Proportions Class 9 Notes & Examples