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Metals and Non-metals - CORROSION3.5 CORROSION3.5 CORROSION3.5 CORROSION3.5 CORROSION

Grade 10CBSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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Corrosion is a process where metals are gradually worn away by the action of air, moisture, or chemicals (like acids) on their surface.

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Silver articles become black after some time when exposed to air because silver reacts with sulfur in the air to form a coating of silver sulphide (Ag2SAg_2S).

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Copper reacts with moist carbon dioxide in the air and slowly loses its shiny brown surface and gains a green coat. This green substance is basic copper carbonate (CuCO3⋅Cu(OH)2CuCO_3 \cdot Cu(OH)_2).

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Iron when exposed to moist air for a long time acquires a coating of a brown flaky substance called rust (Fe2O3⋅xH2OFe_2O_3 \cdot xH_2O).

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Both air (oxygen) and moisture (water) are essential conditions for the rusting of iron.

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Prevention of corrosion can be achieved by painting, oiling, greasing, galvanising, chrome plating, anodising, or making alloys.

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Galvanisation is a method of protecting steel and iron from rusting by coating them with a thin layer of zinc (ZnZn). The galvanized article is protected even if the zinc coating is broken.

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Alloying is a very good method of improving the properties of a metal. An alloy is a homogeneous mixture of two or more metals, or a metal and a non-metal. For example, Iron (FeFe) mixed with Nickel (NiNi) and Chromium (CrCr) gives stainless steel, which is hard and does not rust.

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If one of the metals in an alloy is mercury (HgHg), then the alloy is called an amalgam.

📐Formulae

4Fe+3O2+2xH2O→2Fe2O3⋅xH2O (Rust)4Fe + 3O_2 + 2xH_2O \rightarrow 2Fe_2O_3 \cdot xH_2O \text{ (Rust)}

2Ag+H2S→Ag2S+H2 (Black coating)2Ag + H_2S \rightarrow Ag_2S + H_2 \text{ (Black coating)}

2Cu+H2O+CO2+O2→CuCO3⋅Cu(OH)2 (Green coating)2Cu + H_2O + CO_2 + O_2 \rightarrow CuCO_3 \cdot Cu(OH)_2 \text{ (Green coating)}

Pure Gold=24 carats\text{Pure Gold} = 24 \text{ carats}

Alloyed Gold (for jewelry)=22 parts Gold+2 parts Cu/Ag\text{Alloyed Gold (for jewelry)} = 22 \text{ parts Gold} + 2 \text{ parts } Cu/Ag

💡Examples

Problem 1:

Explain why a copper vessel loses its shine and acquires a green coating when exposed to air.

Solution:

Copper reacts with the moist carbon dioxide (CO2CO_2) present in the air to form basic copper carbonate (CuCO3⋅Cu(OH)2CuCO_3 \cdot Cu(OH)_2).

Explanation:

The formation of this green layer of basic copper carbonate covers the shiny brown surface of the copper metal, leading to the loss of its characteristic metallic luster.

Problem 2:

An iron nail is placed in a test tube containing anhydrous calcium chloride (CaCl2CaCl_2). Will it rust?

Solution:

No, the iron nail will not rust.

Explanation:

Anhydrous CaCl2CaCl_2 acts as a drying agent and absorbs any moisture present in the air inside the test tube. Since rusting requires both oxygen and moisture, the absence of moisture prevents the chemical reaction 4Fe+3O2+2xH2O→2Fe2O3⋅xH2O4Fe + 3O_2 + 2xH_2O \rightarrow 2Fe_2O_3 \cdot xH_2O.

Problem 3:

Define an alloy and give the composition of Brass and Bronze.

Solution:

An alloy is a homogeneous mixture of two or more metals, or a metal and a non-metal.

  • Brass: Cu+ZnCu + Zn
  • Bronze: Cu+SnCu + Sn

Explanation:

Alloying changes the physical properties like electrical conductivity and melting point. For instance, Brass and Bronze are not as good conductors of electricity as pure copper (CuCu).