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Carbon and its Compounds - CHEMICAL PROPERTIES OF CARBON COMPOUNDS

Grade 10CBSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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Combustion: Carbon and its compounds burn in the presence of oxygen to produce CO2CO_2, water vapor, heat, and light. Saturated hydrocarbons generally give a clean blue flame, while unsaturated hydrocarbons give a yellow sooty flame due to incomplete combustion.

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Oxidation: Carbon compounds can be easily oxidized. For example, alcohols are converted to carboxylic acids using oxidizing agents like alkaline KMnO4KMnO_4 (Potassium Permanganate) or acidified K2Cr2O7K_2Cr_2O_7 (Potassium Dichromate).

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Addition Reaction: Unsaturated hydrocarbons add hydrogen in the presence of catalysts like NiNi or PdPd to form saturated hydrocarbons. This process is called hydrogenation and is used to convert vegetable oils (unsaturated) into vegetable ghee (saturated).

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Substitution Reaction: In saturated hydrocarbons, hydrogen atoms can be replaced by other atoms like chlorine in the presence of sunlight. This is a rapid reaction yielding a series of products.

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Esterification: The reaction between an alcohol and a carboxylic acid in the presence of an acid catalyst to produce a sweet-smelling substance called an ester.

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Saponification: The reaction of an ester with a base like NaOHNaOH to produce the parent alcohol and the sodium salt of the carboxylic acid (soap).

📐Formulae

CH4+2O2→CO2+2H2O+Heat + LightCH_4 + 2O_2 \rightarrow CO_2 + 2H_2O + \text{Heat + Light}

CH3CH2OH→or Acidified K2Cr2O7+HeatAlkaline KMnO4+HeatCH3COOHCH_3CH_2OH \xrightarrow[\text{or Acidified } K_2Cr_2O_7 + \text{Heat}]{\text{Alkaline } KMnO_4 + \text{Heat}} CH_3COOH

CH2=CH2+H2→Ni/PdCH3−CH3CH_2=CH_2 + H_2 \xrightarrow{Ni/Pd} CH_3-CH_3

CH4+Cl2→SunlightCH3Cl+HClCH_4 + Cl_2 \xrightarrow{\text{Sunlight}} CH_3Cl + HCl

CH3COOH+CH3CH2OH→AcidCH3COOCH2CH3+H2OCH_3COOH + CH_3CH_2OH \xrightarrow{\text{Acid}} CH_3COOCH_2CH_3 + H_2O

2Na+2CH3CH2OH→2CH3CH2ONa+H2↑2Na + 2CH_3CH_2OH \rightarrow 2CH_3CH_2ONa + H_2 \uparrow

CH3COOC2H5→NaOHC2H5OH+CH3COONaCH_3COOC_2H_5 \xrightarrow{NaOH} C_2H_5OH + CH_3COONa

💡Examples

Problem 1:

Identify the product formed when CH3CH2OHCH_3CH_2OH reacts with alkaline KMnO4KMnO_4 and heat.

Solution:

CH3COOHCH_3COOH (Ethanoic acid)

Explanation:

Alkaline KMnO4KMnO_4 acts as a strong oxidizing agent. It adds oxygen to Ethanol (CH3CH2OHCH_3CH_2OH) to convert the hydroxyl group into a carboxyl group, resulting in Ethanoic acid (CH3COOHCH_3COOH).

Problem 2:

Explain the reaction used to test for unsaturation in hydrocarbons using Bromine water.

Solution:

CnH2n+Br2→CnH2nBr2C_nH_{2n} + Br_2 \rightarrow C_nH_{2n}Br_2

Explanation:

Unsaturated hydrocarbons (alkenes/alkynes) undergo an Addition Reaction with Bromine water (Br2Br_2). The reddish-brown color of bromine disappears (decolorization) as it adds across the double or triple bond, while saturated hydrocarbons do not react with bromine water under normal conditions.

Problem 3:

Write the chemical equation for the reaction between Ethanoic acid and Sodium Carbonate.

Solution:

2CH3COOH+Na2CO3→2CH3COONa+H2O+CO22CH_3COOH + Na_2CO_3 \rightarrow 2CH_3COONa + H_2O + CO_2

Explanation:

Ethanoic acid reacts with carbonates to produce a salt (Sodium Ethanoate), water, and Carbon Dioxide gas. The evolution of CO2CO_2 causes brisk effervescence.