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Aldehydes, Ketones and Carboxylic Acids

Each subtopic includes About section, revision page link, 10 preview questions, and practice CTAs.

Nomenclature and nature of carbonyl group

Subtopic

Nomenclature and nature of carbonyl group under Aldehydes, Ketones and Carboxylic Acids for Grade 12 ICSE.

About Topic & Revision

Preview questions (no answers)

  1. 1.

    The common name for the simplest aldehyde, Methanal, is:

    A.

    Acetaldehyde

    B.

    Propionaldehyde

    C.

    Formaldehyde

    D.

    Formic acid

  2. 2.

    The hybridization of the carbon atom in the carbonyl group (>C=O>C=O) is:

    A.

    sp2sp^2

    B.

    spsp

    C.

    sp3sp^3

    D.

    dsp2dsp^2

  3. 3.

    Which of the following functional groups characterizes a carboxylic acid?

    A.

    βˆ’CHO-CHO

    B.

    βˆ’COβˆ’-CO-

    C.

    βˆ’COOH-COOH

    D.

    βˆ’OH-OH

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Nomenclature and nature of carbonyl group to practice offline. It includes additional chapter-level practice questions.

Methods of preparation

Subtopic

Methods of preparation under Aldehydes, Ketones and Carboxylic Acids for Grade 12 ICSE.

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Preview questions (no answers)

  1. 1.

    What is the product formed when Methyl cyanide (CH3CNCH_3CN) undergoes complete hydrolysis in the presence of an acid?

    A.

    Ethanal

    B.

    Ethanoic acid

    C.

    Methanoic acid

    D.

    Acetone

  2. 2.

    Which reagent is commonly used to selectively oxidize primary alcohols to aldehydes without further oxidation to carboxylic acids?

    A.

    Acidified K2Cr2O7K_2Cr_2O_7

    B.

    Alkaline KMnO4KMnO_4

    C.

    Pyridinium chlorochromate (PCC)

    D.

    Concentrated HNO3HNO_3

  3. 3.

    To prepare propanone from propan-2-ol, which of the following reagents is most suitable for oxidation?

    A.

    LiAlH4LiAlH_4

    B.

    CrO3CrO_3 in anhydrous medium

    C.

    Znβˆ’Hg/HClZn-Hg/HCl

    D.

    H2/NiH_2/Ni

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Methods of preparation to practice offline. It includes additional chapter-level practice questions.

Physical and chemical properties

Subtopic

Physical and chemical properties under Aldehydes, Ketones and Carboxylic Acids for Grade 12 ICSE.

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Preview questions (no answers)

  1. 1.

    Which of the following carboxylic acids is most soluble in water at room temperature?

    A.

    Ethanoic acid

    B.

    Hexanoic acid

    C.

    Benzoic acid

    D.

    Butanoic acid

  2. 2.

    Formalin, used for preserving biological specimens, is an aqueous solution containing approximately what percentage of formaldehyde?

    A.

    10%

    B.

    25%

    C.

    40%

    D.

    95%

  3. 3.

    Which reagent is used to distinguish between Aldehydes and Ketones by forming a shiny metallic mirror on the inner walls of the test tube?

    A.

    Fehling's solution

    B.

    Schiff's reagent

    C.

    Tollen's reagent

    D.

    Lucas reagent

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Physical and chemical properties to practice offline. It includes additional chapter-level practice questions.

Mechanism of nucleophilic addition

Subtopic

Mechanism of nucleophilic addition under Aldehydes, Ketones and Carboxylic Acids for Grade 12 ICSE.

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Preview questions (no answers)

  1. 1.

    Which of the following is the first step in the base-catalyzed nucleophilic addition of HCNHCN to a carbonyl compound?

    A.

    Protonation of the carbonyl oxygen

    B.

    Attack of the cyanide ion on the carbonyl carbon

    C.

    Formation of a carbocation

    D.

    Elimination of a water molecule

  2. 2.

    In the structure of a carbonyl group, the carbon atom behaves as a/an:

    A.

    Nucleophile due to high electron density

    B.

    Electrophile due to partial positive charge

    C.

    Lewis base

    D.

    Free radical

  3. 3.

    Which of the following factors makes aldehydes generally more reactive than ketones towards nucleophilic addition reactions?

    A.

    Only steric effect

    B.

    Only inductive effect

    C.

    Both steric and inductive effects

    D.

    Neither steric nor inductive effects

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Mechanism of nucleophilic addition to practice offline. It includes additional chapter-level practice questions.

Alpha hydrogen reactivity in aldehydes

Subtopic

Alpha hydrogen reactivity in aldehydes under Aldehydes, Ketones and Carboxylic Acids for Grade 12 ICSE.

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Preview questions (no answers)

  1. 1.

    Aldol condensation is a characteristic reaction of aldehydes and ketones containing at least one:

    A.

    Ξ²\beta-hydrogen atom

    B.

    Ξ³\gamma-hydrogen atom

    C.

    Ξ±\alpha-hydrogen atom

    D.

    delta\\delta-hydrogen atom

  2. 2.

    What is the IUPAC name of the product formed by the self-condensation of ethanal in the presence of dilute alkali?

    A.

    2-Hydroxybutanal

    B.

    3-Hydroxybutanal

    C.

    But-2-enal

    D.

    Propan-2-one

  3. 3.

    Which of the following compounds will NOT undergo Aldol condensation when treated with dilute NaOHNaOH?

    A.

    CH3CHOCH_{3}CHO

    B.

    CH3CH2CHOCH_{3}CH_{2}CHO

    C.

    C6H5CHOC_{6}H_{5}CHO

    D.

    CH3COCH3CH_{3}COCH_{3}

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Alpha hydrogen reactivity in aldehydes to practice offline. It includes additional chapter-level practice questions.

Uses of aldehydes and ketones

Subtopic

Uses of aldehydes and ketones under Aldehydes, Ketones and Carboxylic Acids for Grade 12 ICSE.

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Preview questions (no answers)

  1. 1.

    Paraldehyde is a cyclic trimer of acetaldehyde. In the field of medicine, it is primarily used as a:

    A.

    Local anesthetic

    B.

    Antipyretic

    C.

    Antibiotic

    D.

    Hypnotic and sedative

  2. 2.

    Benzaldehyde is an aromatic aldehyde widely used in the food and perfume industries. What characteristic odor is associated with this compound?

    A.

    Rotten eggs

    B.

    Fruity smell

    C.

    Bitter almonds

    D.

    Vinegar

  3. 3.

    Which of the following ketones is most commonly used as a household solvent for removing nail polish and as a cleaning agent for electronic components?

    A.

    Propanone

    B.

    Butanone

    C.

    Pentan-3-one

    D.

    Acetophenone

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Uses of aldehydes and ketones to practice offline. It includes additional chapter-level practice questions.

Acidity of carboxylic acids

Subtopic

Acidity of carboxylic acids under Aldehydes, Ketones and Carboxylic Acids for Grade 12 ICSE.

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Preview questions (no answers)

  1. 1.

    A higher value of KaK_a (acid dissociation constant) for a carboxylic acid indicates that the acid is:

    A.

    Stronger

    B.

    Weaker

    C.

    Neutral

    D.

    Highly concentrated

  2. 2.

    The acidity of carboxylic acids is primarily due to the resonance stabilization of which species formed after dissociation?

    A.

    Carbocation

    B.

    Carbanion

    C.

    Carboxylate ion

    D.

    Alkoxide ion

  3. 3.

    Arrange the following in the decreasing order of their acidic strength: (I) HCOOHHCOOH, (II) CH3COOHCH_3COOH, (III) CH3CH2COOHCH_3CH_2COOH

    A.

    I > II > III

    B.

    III > II > I

    C.

    II > I > III

    D.

    I > III > II

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Acidity of carboxylic acids to practice offline. It includes additional chapter-level practice questions.

Aldehydes, Ketones and Carboxylic Acids - Class 12 Chemistry (ICSE) | Krit.club