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Aldehydes, Ketones and Carboxylic Acids

Each subtopic includes About section, revision page link, 10 preview questions, and practice CTAs.

Nomenclature and Structure of Carbonyl Group

Subtopic

Nomenclature and Structure of Carbonyl Group under Aldehydes, Ketones and Carboxylic Acids for Grade 12 CBSE.

About Topic & Revision

Preview questions (no answers)

  1. 1.

    In the carbonyl group, the carbon-oxygen double bond consists of three σ\sigma bonds and one π\pi bond. What is the approximate bond angle around the carbon atom?

    A.

    180180^\circ

    B.

    109.5109.5^\circ

    C.

    9090^\circ

    D.

    120120^\circ

  2. 2.

    The common name for the simplest ketone, Propan-2-one, is:

    A.

    Acetone

    B.

    Acetaldehyde

    C.

    Ethyl methyl ketone

    D.

    Diethyl ketone

  3. 3.

    Which of the following is the correct IUPAC name for the simplest aldehyde, HCHOHCHO?

    A.

    Ethanal

    B.

    Formaldehyde

    C.

    Methanal

    D.

    Methanol

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Nomenclature and Structure of Carbonyl Group to practice offline. It includes additional chapter-level practice questions.

Preparation of Aldehydes and Ketones

Subtopic

Preparation of Aldehydes and Ketones under Aldehydes, Ketones and Carboxylic Acids for Grade 12 CBSE.

About Topic & Revision

Preview questions (no answers)

  1. 1.

    Which reaction is used to prepare aldehydes from nitriles using stannous chloride and hydrochloric acid followed by hydrolysis?

    A.

    Etard reaction

    B.

    Gatterman-Koch reaction

    C.

    Cannizzaro reaction

    D.

    Stephen reaction

  2. 2.

    The Etard reaction involves the oxidation of toluene to benzaldehyde using which specific reagent?

    A.

    Alkaline KMnO4KMnO_4

    B.

    Acidified K2Cr2O7K_2Cr_2O_7

    C.

    Chromyl chloride (CrO2Cl2CrO_2Cl_2) in CS2CS_2

    D.

    Anhydrous CrO3CrO_3 in acetic anhydride

  3. 3.

    Hydration of ethyne (CHCHCH \equiv CH) in the presence of H2SO4H_2SO_4 and HgSO4HgSO_4 at 333K333\,K yields which of the following products?

    A.

    Methanol

    B.

    Ethanal

    C.

    Propanone

    D.

    Ethanol

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Preparation of Aldehydes and Ketones to practice offline. It includes additional chapter-level practice questions.

Physical and Chemical Properties

Subtopic

Physical and Chemical Properties under Aldehydes, Ketones and Carboxylic Acids for Grade 12 CBSE.

About Topic & Revision

Preview questions (no answers)

  1. 1.

    Which of the following compounds will give a positive Iodoform test (yellow precipitate with I2I_2 and NaOHNaOH)?

    A.

    Pentan-3-one

    B.

    Benzophenone

    C.

    Acetophenone

    D.

    Methanol

  2. 2.

    Lower carboxylic acids are soluble in water primarily due to:

    A.

    High molecular mass

    B.

    Formation of hydrogen bonds with water molecules

    C.

    The presence of a hydrophobic hydrocarbon chain

    D.

    London dispersion forces

  3. 3.

    The reagent used to distinguish between aldehydes and ketones is:

    A.

    Tollen's reagent

    B.

    Fehling's solution

    C.

    Schiff's reagent

    D.

    All of these

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Physical and Chemical Properties to practice offline. It includes additional chapter-level practice questions.

Nucleophilic Addition Reactions

Subtopic

Nucleophilic Addition Reactions under Aldehydes, Ketones and Carboxylic Acids for Grade 12 CBSE.

About Topic & Revision

Preview questions (no answers)

  1. 1.

    The reaction of an aldehyde with one equivalent of a monohydric alcohol in the presence of dry hydrogen chloride gas yields:

    A.

    An acetal

    B.

    An ether

    C.

    A hemiacetal

    D.

    An ester

  2. 2.

    Which of the following reagents is used to form a cyanohydrin from an aldehyde or ketone?

    A.

    NH2OH/H+NH_2OH / H^+

    B.

    HCN/OHHCN / OH^-

    C.

    NaHSO3NaHSO_3

    D.

    RMgXRMgX

  3. 3.

    During the nucleophilic addition of a nucleophile (NuNu^-) to a carbonyl group, what is the change in hybridization of the carbonyl carbon atom?

    A.

    From sp3sp^3 to sp2sp^2

    B.

    From spsp to sp2sp^2

    C.

    From sp2sp^2 to sp3sp^3

    D.

    From sp2sp^2 to spsp

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Nucleophilic Addition Reactions to practice offline. It includes additional chapter-level practice questions.

Acidity of Carboxylic Acids

Subtopic

Acidity of Carboxylic Acids under Aldehydes, Ketones and Carboxylic Acids for Grade 12 CBSE.

About Topic & Revision

Preview questions (no answers)

  1. 1.

    What is the effect of an electron-donating group (EDG) on the acidity of a carboxylic acid?

    A.

    It increases the acidity by stabilizing the carboxylate ion.

    B.

    It decreases the acidity by destabilizing the carboxylate ion.

    C.

    It has no effect on the acidity.

    D.

    It increases the KaK_{a} value of the acid.

  2. 2.

    The correct increasing order of acidity for the following compounds is: (I) CH3CH2COOHCH_{3}CH_{2}COOH, (II) CH3COOHCH_{3}COOH, (III) HCOOHHCOOH.

    A.

    I < II < III

    B.

    III < II < I

    C.

    II < I < III

    D.

    I < III < II

  3. 3.

    Carboxylic acids are more acidic than phenols because:

    A.

    The carboxylate ion is stabilized by two equivalent resonance structures where the negative charge is on oxygen atoms.

    B.

    The phenoxide ion is more resonance stabilized than the carboxylate ion.

    C.

    Carboxylic acids have a higher molecular mass than phenols.

    D.

    Phenols contain an aromatic ring which decreases acidity.

Download the worksheet for Aldehydes, Ketones and Carboxylic Acids - Acidity of Carboxylic Acids to practice offline. It includes additional chapter-level practice questions.