Aldehydes, Ketones and Carboxylic Acids

What is the IUPAC name of the following compound: $HOOC-CH_{2}-COOH$?

How many $\sigma$ and $\pi$ bonds are present in the $C=O$ part of the carbonyl group?

What is the IUPAC name of the compound $CH_{3}CH_{2}CH_{2}CH_{2}CHO$?

Which of the following is the prefix for the $-COOH$ group when another group has higher priority?

The common name for $CH_3CH_2CHO$ is:

What is the IUPAC name for the unsaturated carboxylic acid $CH_2=CH-COOH$?

In the nomenclature of ketones, the parent chain is numbered such that the carbonyl carbon gets:

What is the IUPAC name for $CH_3-C \equiv C-CHO$?

When naming aromatic ketones like Benzophenone, the IUPAC name is based on the 'one' suffix. Benzophenone is:

The IUPAC name of $\alpha$-methylbutyraldehyde is:

Which of the following reagents will convert an acyl chloride into a ketone?

What is the product when but-1-yne is treated with $HgSO_4$ and $H_2SO_4$?

The reduction of a nitrile to an imine is the first step of which named reaction?

Acetophenone can be prepared by the reaction of benzene with which of the following in the presence of anhydrous $AlCl_3$?

An organic compound $Z$ is synthesized from $2$-bromopropane through the reaction sequence shown in the diagram. In Step 1, $2$-bromopropane reacts with $Mg$ in dry ether to form a Grignard reagent $X$. In Step 2, $X$ reacts with ethanenitrile ($CH_3CN$) to form an intermediate $Y$, which is then hydrolyzed in Step 3 to yield the final ketone $Z$. Identify the IUPAC name of $Z$.

Ozonolysis of $2,3$-dimethylbut-2-ene yields:

In the catalytic dehydrogenation of primary alcohols to aldehydes, which metal is used as a catalyst at $573\,K$?

When vapors of 2-methylpropan-2-ol are passed over heated copper at $573 K$, the product obtained is:

Why is formyl chloride not a standard reagent for Friedel-Crafts formylation to produce benzaldehyde?

What is the result of treating $p$-nitrotoluene with $CrO_2Cl_2$ in $CS_2$ followed by hydrolysis?

Dry distillation of calcium acetate gives:

Gatterman-Koch reaction is used to synthesize:

A ketone reacts with semicarbazide to form a:

Which of the following has the lowest $pK_a$ value?

The acidity of carboxylic acids can be explained by the stability of the carboxylate ion due to:

Which of the following will give a positive test with Fehling's solution?

In the oxidation of unsymmetrical ketones by strong oxidizing agents, the cleavage of the $C-C$ bond occurs such that the carbonyl group stays with the smaller alkyl group. This is known as:

A multi-step synthesis is performed starting with 4-oxopentanoic acid. The compound is first treated with ethylene glycol in the presence of dry $HCl$ gas to form Compound A. Compound A is then reacted with $LiAlH_4$ in anhydrous ether, and the resulting mixture is finally treated with dilute $H_3O^+$ to yield the organic product Z. What is the IUPAC name of product Z?

The Wolff-Kishner reduction is not suitable for which of the following compounds?

When Acetic acid is reacted with Chlorine in the presence of Red Phosphorus, and the product is further treated with excess of Ammonia, the final organic product is:

In the reaction of propanone with methyl magnesium bromide, the carbon of the Grignard reagent attacks:

Which group increases the reactivity of a carbonyl group towards nucleophilic addition when attached to the carbonyl carbon?

The reaction between a carbonyl compound and 2,4-DNP involves the elimination of:

When an aldehyde is treated with excess alcohol and dry $HCl$, the final product is:

When an aldehyde reacts with hydrazine and then with $KOH$ and ethylene glycol (Wolff-Kishner reduction), the carbonyl group is converted to:

The addition of Grignard reagent to a carbonyl group is followed by hydrolysis. The source of the 'H' atom that attaches to the oxygen in the resulting alcohol is:

What is the correct order of nucleophilicity for the following species in the reaction with a carbonyl group?

Which of the following gives an addition product with $NH_3$ that is a complex cyclic compound called urotropine?

In the reaction of a ketone with a primary amine, the intermediate carbinolamine loses water to form an imine. Which factor most influences the ease of this dehydration step?

Which of the following will have the highest percentage of hydrate at equilibrium in water?

Carboxylic acids are known to be more acidic than many other organic compounds because they can easily donate a proton to form a resonance-stabilized anion. Based on the dissociation flowchart provided, what is the general chemical name for the anion represented as 'Species B'?

Among the following, which one does NOT react with sodium bicarbonate to give carbon dioxide?

Which of the following groups, if substituted in benzoic acid, will increase its $K_{a}$ value?

The inductive effect of a halogen atom on the acidity of a carboxylic acid is known as:

Which of the following correctly identifies the role of the phenyl group in benzoic acid compared to the methyl group in acetic acid?

In a comparison between ethanoic acid and propanoic acid, which statement is true?

How does the $pK_{a}$ of $m$-chlorobenzoic acid compare to $p$-chlorobenzoic acid?

Consider the acid strength of the following four carboxylic acids: (I) $C_{6}H_{5}COOH$ (II) $C_{6}H_{5}CH_{2}COOH$ (III) $p-O_{2}NC_{6}H_{4}COOH$ (IV) $p-O_{2}NC_{6}H_{4}CH_{2}COOH$

Which of the following represents the correct decreasing order of their acid strength?

Consider the acidities of the following three acids: (X) $CH_{3}COOH$, (Y) $CH_{2}ClCOOH$, (Z) $CHCl_{2}COOH$. The correct order of their $pH$ values for $0.1M$ solutions is:

Which of the following explains why p-nitrophenol has a $pK_{a}$ of 7.15, whereas p-nitrobenzoic acid has a $pK_{a}$ of 3.44?

When Propyl benzene is treated with alkaline $KMnO_4$ and then acidified, the product is:

Identify the reagent required for the step $C_6H_5MgBr \rightarrow C_6H_5COOMgBr$:

Which of the following will not yield a carboxylic acid on simple hydrolysis?

The conversion of $R-CN \rightarrow R-COOH$ involves how many steps of hydrolysis?

Oxidation of 1-phenylethanol with acidic $KMnO_{4}$ gives:

Which of the following cannot be used to oxidize an aldehyde to a carboxylic acid?

Preparation of carboxylic acids from Grignard reagents and nitriles are methods used to:

In the sequence $C_{2}H_{5}Br \xrightarrow{AgCN} X \xrightarrow{H_{3}O^{+}} Y$, the product 'Y' is:

Reaction of an alkene with hot alkaline $KMnO_{4}$ followed by acidification yields carboxylic acids. If the alkene is 2-methylbut-2-ene, the products are:

Which statement is true regarding the oxidation of $1^{\circ}$ alcohols with $KMnO_{4}$?

Acetone is a starting material for the synthesis of which of the following plastics?

Which of the following is a use of Benzoic acid in medicine?

Ethanoic acid is used in the preparation of which common food item?

Which ketone is used in the preparation of Iodoform?

Acetaldehyde ($CH_3CHO$) is a versatile starting material in industrial chemistry. Which of the following compounds, synthesized from acetaldehyde, is widely used as a monomer in the production of polymers found in common adhesives and latex-based paints?

Which chemical is used to produce urea-formaldehyde resins for plywood adhesives?

Identify the acid used in the production of dyes like indigo.

Sodium formate, the salt of formic acid, is used in the textile industry. What is its function in the dyeing process?

Acetone is used as a precursor for the synthesis of 'Bisphenol A' (BPA). What is the primary application of BPA?

Sebacic acid is a dicarboxylic acid used in the production of which specific polymer?