krit.club logo

Chemistry of the Environment - Air quality and pollutants

Grade 11IGCSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Clean, dry air is a mixture containing approximately 78%78\% Nitrogen (N2N_2), 21%21\% Oxygen (O2O_2), and the remaining 1%1\% consists of noble gases (mainly Argon ArAr), Carbon Dioxide (CO2CO_2), and water vapor.

Carbon Monoxide (COCO) is a toxic pollutant formed by the incomplete combustion of carbon-containing fuels. It binds to hemoglobin in the blood, preventing the transport of O2O_2.

Sulfur Dioxide (SO2SO_2) is produced by the combustion of fossil fuels containing sulfur impurities and by volcanic activity. It leads to acid rain by forming H2SO4H_2SO_4.

Oxides of Nitrogen (NOxNO_x) are formed in car engines where high temperatures and pressures cause N2N_2 and O2O_2 from the air to react. They contribute to photochemical smog and acid rain (HNO3HNO_3).

Catalytic converters in vehicles use transition metal catalysts (like Platinum or Rhodium) to convert harmful gases like COCO and NONO into less harmful CO2CO_2 and N2N_2.

The Greenhouse Effect is caused by gases like CO2CO_2 and CH4CH_4 (Methane) absorbing thermal energy (infrared radiation) reflected from the Earth's surface, leading to global warming.

Photosynthesis is the process by which plants remove CO2CO_2 from the atmosphere: 6CO2+6H2OC6H12O6+6O26CO_2 + 6H_2O \rightarrow C_6H_{12}O_6 + 6O_2.

📐Formulae

N2(g)+O2(g)2NO(g)N_2(g) + O_2(g) \rightarrow 2NO(g) (Formation of Nitrogen Monoxide in engines)

2CO(g)+2NO(g)2CO2(g)+N2(g)2CO(g) + 2NO(g) \rightarrow 2CO_2(g) + N_2(g) (Reaction in a catalytic converter)

S+O2SO2S + O_2 \rightarrow SO_2 (Combustion of sulfur impurities)

2SO2+O2+2H2O2H2SO42SO_2 + O_2 + 2H_2O \rightarrow 2H_2SO_4 (Formation of sulfuric acid rain)

CH4+2O2CO2+2H2OCH_4 + 2O_2 \rightarrow CO_2 + 2H_2O (Complete combustion of methane)

💡Examples

Problem 1:

Identify the gas responsible for the 'Greenhouse Effect' produced during the decomposition of vegetation in the absence of oxygen, and provide its formula.

Solution:

Methane, CH4CH_4.

Explanation:

Anaerobic decomposition (decomposition without oxygen), such as in rice paddy fields or landfill sites, produces methane, which is a potent greenhouse gas.

Problem 2:

State how a catalytic converter removes Nitrogen Monoxide (NONO) from exhaust fumes.

Solution:

By reacting it with Carbon Monoxide (COCO) to produce N2N_2 and CO2CO_2: 2CO+2NO2CO2+N22CO + 2NO \rightarrow 2CO_2 + N_2

Explanation:

The catalytic converter facilitates a redox reaction where Nitrogen Monoxide is reduced to Nitrogen gas and Carbon Monoxide is oxidized to Carbon Dioxide.

Problem 3:

Explain why the presence of Lead (PbPb) compounds in the atmosphere has decreased in many countries.

Solution:

The transition from leaded to unleaded petrol (gasolinegasoline).

Explanation:

Lead compounds were previously added to petrol to improve engine performance, but they are toxic and cause brain damage, leading to a global shift toward lead-free fuels.

Air quality and pollutants - Revision Notes & Key Formulas | IGCSE Grade 11 Chemistry