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Environmental Chemistry - Water and Soil Pollution

Grade 11ICSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Water Pollution: Presence of undesirable substances such as pathogens, organic wastes, and chemical pollutants (heavy metals like Pb2+Pb^{2+}, Hg2+Hg^{2+}, and Cd2+Cd^{2+}) in water bodies.

Dissolved Oxygen (DO): The amount of oxygen dissolved in water, essential for aquatic life. The concentration of DO in cold water can reach up to 10 ppm10\text{ ppm}. If it drops below 6 ppm6\text{ ppm}, the growth of fish is inhibited.

Biochemical Oxygen Demand (BOD): The amount of oxygen required by bacteria to break down the organic matter in a certain volume of a water sample over five days. Clean water has a BOD value of less than 5 ppm5\text{ ppm}, whereas highly polluted water can have a BOD of 17 ppm17\text{ ppm} or more.

Chemical Oxygen Demand (COD): A measure of the oxygen required to oxidize all organic matter (biodegradable and non-biodegradable) in water using a strong oxidizing agent like acidified K2Cr2O7K_2Cr_2O_7.

Eutrophication: The process where water bodies receive excess nutrients, specifically phosphates (PO43PO_4^{3-}) and nitrates (NO3NO_3^-), leading to dense plant growth (algal blooms) and depletion of dissolved oxygen.

Soil Pollution: Contamination caused by the excessive use of synthetic fertilizers, pesticides (insecticides like DDTDDT, herbicides like NaClO3NaClO_3), and industrial effluents containing heavy metals.

Biomagnification: The increase in the concentration of non-biodegradable toxic substances (e.g., Mercury or DDTDDT) as they move up the food chain.

Pesticides and Herbicides: Chemicals like Organochlorines (e.g., DDTDDT), Organophosphates, and herbicides like Sodium chlorate (NaClO3NaClO_3) and Sodium arsentite (Na3AsO3Na_3AsO_3).

📐Formulae

CH2O(organic matter)+O2bacteriaCO2+H2OCH_2O(organic\ matter) + O_2 \xrightarrow{bacteria} CO_2 + H_2O

BOD=DOinitialDOfinal (measured over 5 days)BOD = DO_{initial} - DO_{final} \text{ (measured over 5 days)}

K2Cr2O7+4H2SO4K2SO4+Cr2(SO4)3+4H2O+3[O]K_2Cr_2O_7 + 4H_2SO_4 \rightarrow K_2SO_4 + Cr_2(SO_4)_3 + 4H_2O + 3[O]

Al3++PO43AlPO4(s) (Precipitation of phosphates)Al^{3+} + PO_4^{3-} \rightarrow AlPO_4(s) \text{ (Precipitation of phosphates)}

💡Examples

Problem 1:

A water sample is collected from a river near a sewage outlet. Upon testing, its DOinitialDO_{initial} was 9.0 ppm9.0\text{ ppm} and after 5 days of incubation at 20C20^\circ C, the DOfinalDO_{final} was 2.0 ppm2.0\text{ ppm}. Calculate the BOD and determine the pollution level.

Solution:

BOD=9.0 ppm2.0 ppm=7.0 ppmBOD = 9.0\text{ ppm} - 2.0\text{ ppm} = 7.0\text{ ppm}.

Explanation:

Since the BOD value (7.0 ppm7.0\text{ ppm}) is greater than 5 ppm5\text{ ppm}, the water is considered moderately polluted. Clean water should have a BOD below 5 ppm5\text{ ppm}.

Problem 2:

Why is DDTDDT considered a dangerous soil and water pollutant even though it is effective against insects?

Solution:

DDTDDT is non-biodegradable and fat-soluble.

Explanation:

Because DDTDDT (C14H9Cl5C_{14}H_9Cl_5) does not decompose easily, it remains in the environment for years. It enters the food chain and undergoes biomagnification, reaching toxic levels in higher trophic levels (like birds and humans), interfering with calcium metabolism.

Problem 3:

What is the role of phosphate detergents in causing 'dead zones' in lakes?

Solution:

They act as nutrients for algae, leading to Eutrophication.

Explanation:

Phosphate ions (PO43PO_4^{3-}) from detergents promote the rapid growth of algae. When these algae die, aerobic bacteria consume large amounts of dissolved oxygen (O2O_2) to decompose them, leaving insufficient oxygen for fish, which leads to their death and the creation of 'dead zones'.

Water and Soil Pollution - Revision Notes & Key Formulas | ICSE Class 11 Chemistry