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Human Influences on Ecosystems - Pollution

Grade 11IGCSEBiology

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Eutrophication: The process where excess nutrients, specifically nitrates (NO3NO_3^-) and phosphates (PO43PO_4^{3-}), leach into water bodies, leading to rapid algal growth, oxygen (O2O_2) depletion, and the death of aquatic organisms.

Greenhouse Effect: The trapping of infrared radiation by gases such as carbon dioxide (CO2CO_2), methane (CH4CH_4), nitrous oxide (N2ON_2O), and CFCsCFCs, leading to an increase in the Earth's mean temperature.

Acid Rain: Formed when sulfur dioxide (SO2SO_2) and oxides of nitrogen (NOxNO_x) dissolve in rainwater to form sulfuric acid (H2SO4H_2SO_4) and nitric acid (HNO3HNO_3), lowering the pHpH of ecosystems.

Bioaccumulation: The buildup of persistent, non-biodegradable chemicals (e.g., heavy metals like Hg2+Hg^{2+} or pesticides like DDTDDT) within the tissues of a single organism over time.

Biomagnification: The increase in concentration of a pollutant as it passes along a food chain to higher trophic levels, often reaching toxic levels in top predators.

Sewage Pollution: Untreated sewage provides a food source for aerobic bacteria, which multiply and consume dissolved oxygen (O2O_2) through respiration, leading to a high Biological Oxygen Demand (BODBOD).

📐Formulae

H2O(l)+SO2(g)H2SO3(aq)H_2O(l) + SO_2(g) \rightarrow H_2SO_3(aq) (Formation of sulfurous acid)

C6H12O6+6O26CO2+6H2O+EnergyC_6H_{12}O_6 + 6O_2 \rightarrow 6CO_2 + 6H_2O + \text{Energy} (Aerobic respiration by decomposers depleting oxygen)

Concentration Factor=Concentration in organismConcentration in environment\text{Concentration Factor} = \frac{\text{Concentration in organism}}{\text{Concentration in environment}}

pH=log10[H+]pH = -\log_{10}[H^+] (Measure of acidity in aquatic environments)

💡Examples

Problem 1:

A farmer applies a nitrogen-based fertilizer containing NH4NO3NH_4NO_3 to a field. Following heavy rain, the concentration of NO3NO_3^- in a nearby pond increases from 2 mg/dm32\text{ mg/dm}^3 to 25 mg/dm325\text{ mg/dm}^3. Describe the biological consequences.

Solution:

This will trigger eutrophication. The high levels of NO3NO_3^- cause an 'algal bloom'. This algae covers the surface, blocking light for submerged plants, preventing photosynthesis. As plants and algae die, aerobic bacteria decompose them, using up dissolved O2O_2. The water becomes anoxic, leading to the death of fish.

Explanation:

The increase in nitrate ions (NO3NO_3^-) acts as a limiting factor for primary producers. The subsequent collapse of the oxygen cycle is a direct result of increased bacterial respiration.

Problem 2:

If a sample of lake water has a hydrogen ion concentration of [H+]=104 mol/dm3[H^+] = 10^{-4}\text{ mol/dm}^3 due to acid rain, calculate the pHpH.

Solution:

pH=log10(104)=4pH = -\log_{10}(10^{-4}) = 4

Explanation:

Normal rainwater has a pHpH of about 5.65.6. A pHpH of 44 is significantly more acidic and can lead to the leaching of aluminum ions (Al3+Al^{3+}) from soil into lakes, which is toxic to fish gills.

Pollution - Revision Notes & Key Diagrams | IGCSE Grade 11 Biology