Review the key concepts, formulae, and examples before starting your quiz.
🔑Concepts
Metals are elements that typically lose electrons to form positive ions (cations), such as or .
Physical properties of metals include high melting and boiling points, malleability, ductility, and high thermal and electrical conductivity due to the presence of a 'sea' of delocalized electrons.
The reactivity series ranks metals from most to least reactive: .
A more reactive metal will displace a less reactive metal from its oxide or salt solution, e.g., .
Metals above carbon in the reactivity series (like ) are extracted using electrolysis; metals below carbon (like ) are extracted by reduction with carbon or carbon monoxide.
Extraction of Iron occurs in a Blast Furnace where Haematite () is reduced by carbon monoxide ().
Extraction of Aluminium involves the electrolysis of alumina () dissolved in molten cryolite () to lower the melting point and improve conductivity.
Alloys are mixtures of a metal with other elements. They are harder than pure metals because different-sized atoms disrupt the regular arrangement of the lattice, preventing layers from sliding over each other.
📐Formulae
💡Examples
Problem 1:
Explain why is extracted using electrolysis rather than reduction with carbon, and provide the ionic half-equation for the process at the cathode.
Solution:
is more reactive than carbon, meaning carbon is not a strong enough reducing agent to displace oxygen from . The half-equation at the cathode is .
Explanation:
In the reactivity series, is placed above . Only metals below carbon can be extracted by heating their oxides with coke. For , energy must be supplied via electricity to break the strong ionic bonds.
Problem 2:
A piece of is added to a solution of . Predict the observation and write the balanced chemical equation.
Solution:
Observation: The blue color of the solution fades, and a reddish-brown solid () deposits on the . Equation: .
Explanation:
Since is higher than in the reactivity series, it is more reactive and displaces ions from the solution. The is oxidized to (colorless) and the is reduced to metal.