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Chemistry - Metals (Properties, extraction, and reactivity series)

Grade 9IGCSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Metals are elements that typically lose electrons to form positive ions (cations), such as Na+Na^+ or Mg2+Mg^{2+}.

Physical properties of metals include high melting and boiling points, malleability, ductility, and high thermal and electrical conductivity due to the presence of a 'sea' of delocalized electrons.

The reactivity series ranks metals from most to least reactive: K>Na>Ca>Mg>Al>C>Zn>Fe>Sn>Pb>H>Cu>Ag>AuK > Na > Ca > Mg > Al > C > Zn > Fe > Sn > Pb > H > Cu > Ag > Au.

A more reactive metal will displace a less reactive metal from its oxide or salt solution, e.g., Mg(s)+CuSO4(aq)MgSO4(aq)+Cu(s)Mg(s) + CuSO_4(aq) \rightarrow MgSO_4(aq) + Cu(s).

Metals above carbon in the reactivity series (like AlAl) are extracted using electrolysis; metals below carbon (like FeFe) are extracted by reduction with carbon or carbon monoxide.

Extraction of Iron occurs in a Blast Furnace where Haematite (Fe2O3Fe_2O_3) is reduced by carbon monoxide (COCO).

Extraction of Aluminium involves the electrolysis of alumina (Al2O3Al_2O_3) dissolved in molten cryolite (Na3AlF6Na_3AlF_6) to lower the melting point and improve conductivity.

Alloys are mixtures of a metal with other elements. They are harder than pure metals because different-sized atoms disrupt the regular arrangement of the lattice, preventing layers from sliding over each other.

📐Formulae

Metal+OxygenMetal OxideMetal + Oxygen \rightarrow Metal \ Oxide

Metal+WaterMetal Hydroxide+H2(g)Metal + Water \rightarrow Metal \ Hydroxide + H_2(g)

Metal+AcidSalt+H2(g)Metal + Acid \rightarrow Salt + H_2(g)

Fe2O3+3CO2Fe+3CO2Fe_2O_3 + 3CO \rightarrow 2Fe + 3CO_2

C+O2CO2(Exothermic reaction providing heat)C + O_2 \rightarrow CO_2 \quad (Exothermic \ reaction \ providing \ heat)

CaCO3CaO+CO2(Thermal decomposition)CaCO_3 \rightarrow CaO + CO_2 \quad (Thermal \ decomposition)

CaO+SiO2CaSiO3(Slag formation)CaO + SiO_2 \rightarrow CaSiO_3 \quad (Slag \ formation)

Al3++3eAl(Reduction at cathode)Al^{3+} + 3e^- \rightarrow Al \quad (Reduction \ at \ cathode)

💡Examples

Problem 1:

Explain why AluminiumAluminium is extracted using electrolysis rather than reduction with carbon, and provide the ionic half-equation for the process at the cathode.

Solution:

AluminiumAluminium is more reactive than carbon, meaning carbon is not a strong enough reducing agent to displace oxygen from Al2O3Al_2O_3. The half-equation at the cathode is Al3++3eAlAl^{3+} + 3e^- \rightarrow Al.

Explanation:

In the reactivity series, AlAl is placed above CC. Only metals below carbon can be extracted by heating their oxides with coke. For AlAl, energy must be supplied via electricity to break the strong ionic bonds.

Problem 2:

A piece of ZincZinc is added to a solution of Copper(II) sulfateCopper(II) \ sulfate. Predict the observation and write the balanced chemical equation.

Solution:

Observation: The blue color of the CuSO4CuSO_4 solution fades, and a reddish-brown solid (CopperCopper) deposits on the ZincZinc. Equation: Zn(s)+CuSO4(aq)ZnSO4(aq)+Cu(s)Zn(s) + CuSO_4(aq) \rightarrow ZnSO_4(aq) + Cu(s).

Explanation:

Since ZnZn is higher than CuCu in the reactivity series, it is more reactive and displaces Cu2+Cu^{2+} ions from the solution. The ZnZn is oxidized to Zn2+Zn^{2+} (colorless) and the Cu2+Cu^{2+} is reduced to CuCu metal.

Metals (Properties, extraction, and reactivity series) Revision - Grade 9 Science IGCSE