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Chemistry - Atoms, elements, and compounds (Atomic structure and bonding)

Grade 9IGCSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Atoms consist of a central nucleus containing protons (p+p^+) and neutrons (n0n^0), surrounded by electrons (ee^-) orbiting in shells or energy levels.

The Atomic Number (ZZ) is the number of protons in the nucleus; the Nucleon Number (AA), or Mass Number, is the total number of protons and neutrons.

Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons, such as 1735Cl^{35}_{17}Cl and 1737Cl^{37}_{17}Cl.

The electronic configuration follows the 2,8,82, 8, 8 rule for the first 20 elements, where the outer shell electrons determine chemical properties.

Ionic Bonding occurs between metals and non-metals through the transfer of electrons, resulting in electrostatic attraction between oppositely charged ions like Na+Na^+ and ClCl^-.

Covalent Bonding occurs between non-metals through the sharing of electron pairs to achieve a stable outer shell, forming molecules like CH4CH_4 or H2OH_2O.

Metallic Bonding is the electrostatic attraction between a lattice of positive metal ions and a 'sea' of delocalized electrons.

Noble gases (Group VIII/0) are unreactive because they possess a full outer shell of electrons (a stable octet, or duplet for HeHe).

📐Formulae

A=Z+nA = Z + n

Ar=(mass of isotope1×%abundance1)+(mass of isotope2×%abundance2)100A_r = \frac{(\text{mass of isotope}_1 \times \% \text{abundance}_1) + (\text{mass of isotope}_2 \times \% \text{abundance}_2)}{100}

Overall Charge=ProtonsElectrons\text{Overall Charge} = \text{Protons} - \text{Electrons}

Xn (where n is the valency/charge, e.g., Mg2+)X^n \text{ (where } n \text{ is the valency/charge, e.g., } Mg^{2+})

💡Examples

Problem 1:

An atom of Potassium has a nucleon number of 3939 and an atomic number of 1919. Calculate the number of neutrons and write its electronic configuration.

Solution:

Neutrons: 3919=2039 - 19 = 20. Electronic configuration: 2,8,8,12, 8, 8, 1.

Explanation:

The number of neutrons is found by subtracting the atomic number (ZZ) from the nucleon number (AA). Potassium (KK) has 1919 electrons, filled as 22 in the 1st shell, 88 in the 2nd, 88 in the 3rd, and the remaining 11 in the 4th.

Problem 2:

Predict the formula for the ionic compound formed between Aluminum (AlAl, Group III) and Oxygen (OO, Group VI).

Solution:

Al2O3Al_2O_3

Explanation:

Aluminum loses 3 electrons to become Al3+Al^{3+}. Oxygen gains 2 electrons to become O2O^{2-}. To balance the charges (+6+6 and 6-6), two Al3+Al^{3+} ions combine with three O2O^{2-} ions.

Problem 3:

Explain the bonding in a molecule of Ammonia (NH3NH_3) using a dot-and-cross diagram description.

Solution:

Nitrogen shares 33 of its 55 valence electrons with three Hydrogen atoms.

Explanation:

Nitrogen (2,52, 5) needs 33 electrons to complete its shell. Each Hydrogen (11) needs 11 electron. Nitrogen forms three single covalent bonds with three Hydrogen atoms, leaving one lone pair of electrons on the Nitrogen atom.