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Chemistry - Hydrogen (Preparation, Properties, Uses)

Grade 8ICSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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Hydrogen is the first element in the periodic table, represented by the symbol HH and atomic number 11. It exists as a diatomic molecule H2H_2.

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In the laboratory, hydrogen is prepared by the action of dilute HClHCl or dilute H2SO4H_2SO_4 on granulated zinc (ZnZn). Granulated zinc is preferred because it contains impurities like copper which act as a catalyst, speeding up the reaction.

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Hydrogen gas is collected by the downward displacement of water because it is nearly insoluble in water and is lighter than air.

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Industrial preparation via the Bosch Process involves two steps: first, producing water gas (CO+H2CO + H_2) by passing steam over red-hot coke at 1000∘C1000^{\circ}C, and second, reacting water gas with excess steam in the presence of Fe2O3Fe_2O_3 and Cr2O3Cr_2O_3 catalysts.

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Hydrogen is a powerful reducing agent. It removes oxygen from metallic oxides like CuOCuO or PbOPbO when passed over them at high temperatures.

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Hydrogenation is the process of adding hydrogen to vegetable oils (unsaturated fats) in the presence of a nickel (NiNi) catalyst at approximately 200∘C200^{\circ}C to form solid vanaspati ghee (saturated fats).

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Hydrogen is highly combustible and burns in air with a pale blue flame to form water (H2OH_2O), but it is not a supporter of combustion.

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The 'Pop' test: A burning wooden splinter brought near a test tube of hydrogen gas will extinguish with a characteristic 'pop' sound, which is a confirmatory test for hydrogen.

📐Formulae

Zn+2HCl→ZnCl2+H2↑Zn + 2HCl \rightarrow ZnCl_2 + H_2 \uparrow

Zn+H2SO4→ZnSO4+H2↑Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2 \uparrow

C+H2O→1000∘C(CO+H2) [Water Gas]C + H_2O \xrightarrow{1000^{\circ}C} (CO + H_2) \text{ [Water Gas]}

2H2+O2→2H2O2H_2 + O_2 \rightarrow 2H_2O

CuO+H2→ΔCu+H2OCuO + H_2 \xrightarrow{\Delta} Cu + H_2O

N2+3H2⇌Fe+Mo450−500∘C2NH3 [Haber’s Process]N_2 + 3H_2 \xrightleftharpoons[Fe + Mo]{450-500^{\circ}C} 2NH_3 \text{ [Haber's Process]}

Cl2+H2→diffused sunlight2HClCl_2 + H_2 \xrightarrow{\text{diffused sunlight}} 2HCl

💡Examples

Problem 1:

Explain why concentrated sulphuric acid (H2SO4H_2SO_4) is not used in the laboratory preparation of hydrogen from zinc.

Solution:

Concentrated H2SO4H_2SO_4 is a strong oxidizing agent. Instead of producing H2H_2 gas, it reacts with zinc to produce sulphur dioxide (SO2SO_2) gas and water.

Explanation:

The reaction follows: Zn+2H2SO4 (conc.)→ZnSO4+SO2+2H2OZn + 2H_2SO_4 \text{ (conc.)} \rightarrow ZnSO_4 + SO_2 + 2H_2O. Since the goal is to produce H2H_2, the oxidizing nature of the concentrated acid interferes with the result.

Problem 2:

What observation is made when H2H_2 gas is passed over heated lead(II) oxide (PbOPbO)?

Solution:

The yellow-colored lead(II) oxide (PbOPbO) is reduced to a greyish-white metallic lead (PbPb), and droplets of water are seen at the cooler parts of the tube.

Explanation:

This is a redox reaction where hydrogen acts as the reducing agent: PbO+H2→Pb+H2OPbO + H_2 \rightarrow Pb + H_2O. The PbOPbO loses oxygen (reduction) and H2H_2 gains oxygen (oxidation).

Problem 3:

Identify the catalyst used in the Haber process and the hydrogenation of oils.

Solution:

In the Haber process, Finely divided Iron (FeFe) is the catalyst with Molybdenum (MoMo) as a promoter. In the hydrogenation of oils, Nickel (NiNi) is used as the catalyst.

Explanation:

Catalysts are substances that increase the rate of a chemical reaction without being consumed. FeFe helps in the synthesis of NH3NH_3 and NiNi helps in converting liquid oils to solid fats.