Review the key concepts, formulae, and examples before starting your quiz.
🔑Concepts
Hydrogen is the first element in the periodic table, represented by the symbol and atomic number . It exists as a diatomic molecule .
In the laboratory, hydrogen is prepared by the action of dilute or dilute on granulated zinc (). Granulated zinc is preferred because it contains impurities like copper which act as a catalyst, speeding up the reaction.
Hydrogen gas is collected by the downward displacement of water because it is nearly insoluble in water and is lighter than air.
Industrial preparation via the Bosch Process involves two steps: first, producing water gas () by passing steam over red-hot coke at , and second, reacting water gas with excess steam in the presence of and catalysts.
Hydrogen is a powerful reducing agent. It removes oxygen from metallic oxides like or when passed over them at high temperatures.
Hydrogenation is the process of adding hydrogen to vegetable oils (unsaturated fats) in the presence of a nickel () catalyst at approximately to form solid vanaspati ghee (saturated fats).
Hydrogen is highly combustible and burns in air with a pale blue flame to form water (), but it is not a supporter of combustion.
The 'Pop' test: A burning wooden splinter brought near a test tube of hydrogen gas will extinguish with a characteristic 'pop' sound, which is a confirmatory test for hydrogen.
📐Formulae
💡Examples
Problem 1:
Explain why concentrated sulphuric acid () is not used in the laboratory preparation of hydrogen from zinc.
Solution:
Concentrated is a strong oxidizing agent. Instead of producing gas, it reacts with zinc to produce sulphur dioxide () gas and water.
Explanation:
The reaction follows: . Since the goal is to produce , the oxidizing nature of the concentrated acid interferes with the result.
Problem 2:
What observation is made when gas is passed over heated lead(II) oxide ()?
Solution:
The yellow-colored lead(II) oxide () is reduced to a greyish-white metallic lead (), and droplets of water are seen at the cooler parts of the tube.
Explanation:
This is a redox reaction where hydrogen acts as the reducing agent: . The loses oxygen (reduction) and gains oxygen (oxidation).
Problem 3:
Identify the catalyst used in the Haber process and the hydrogenation of oils.
Solution:
In the Haber process, Finely divided Iron () is the catalyst with Molybdenum () as a promoter. In the hydrogenation of oils, Nickel () is used as the catalyst.
Explanation:
Catalysts are substances that increase the rate of a chemical reaction without being consumed. helps in the synthesis of and helps in converting liquid oils to solid fats.