krit.club logo

Chemistry - Hydrogen (Preparation, Properties, Uses)

Grade 8ICSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Hydrogen is the first element in the periodic table, represented by the symbol HH and atomic number 11. It exists as a diatomic molecule H2H_2.

In the laboratory, hydrogen is prepared by the action of dilute HClHCl or dilute H2SO4H_2SO_4 on granulated zinc (ZnZn). Granulated zinc is preferred because it contains impurities like copper which act as a catalyst, speeding up the reaction.

Hydrogen gas is collected by the downward displacement of water because it is nearly insoluble in water and is lighter than air.

Industrial preparation via the Bosch Process involves two steps: first, producing water gas (CO+H2CO + H_2) by passing steam over red-hot coke at 1000C1000^{\circ}C, and second, reacting water gas with excess steam in the presence of Fe2O3Fe_2O_3 and Cr2O3Cr_2O_3 catalysts.

Hydrogen is a powerful reducing agent. It removes oxygen from metallic oxides like CuOCuO or PbOPbO when passed over them at high temperatures.

Hydrogenation is the process of adding hydrogen to vegetable oils (unsaturated fats) in the presence of a nickel (NiNi) catalyst at approximately 200C200^{\circ}C to form solid vanaspati ghee (saturated fats).

Hydrogen is highly combustible and burns in air with a pale blue flame to form water (H2OH_2O), but it is not a supporter of combustion.

The 'Pop' test: A burning wooden splinter brought near a test tube of hydrogen gas will extinguish with a characteristic 'pop' sound, which is a confirmatory test for hydrogen.

📐Formulae

Zn+2HClZnCl2+H2Zn + 2HCl \rightarrow ZnCl_2 + H_2 \uparrow

Zn+H2SO4ZnSO4+H2Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2 \uparrow

C+H2O1000C(CO+H2) [Water Gas]C + H_2O \xrightarrow{1000^{\circ}C} (CO + H_2) \text{ [Water Gas]}

2H2+O22H2O2H_2 + O_2 \rightarrow 2H_2O

CuO+H2ΔCu+H2OCuO + H_2 \xrightarrow{\Delta} Cu + H_2O

N2+3H2Fe+Mo450500C2NH3 [Haber’s Process]N_2 + 3H_2 \xrightleftharpoons[Fe + Mo]{450-500^{\circ}C} 2NH_3 \text{ [Haber's Process]}

Cl2+H2diffused sunlight2HClCl_2 + H_2 \xrightarrow{\text{diffused sunlight}} 2HCl

💡Examples

Problem 1:

Explain why concentrated sulphuric acid (H2SO4H_2SO_4) is not used in the laboratory preparation of hydrogen from zinc.

Solution:

Concentrated H2SO4H_2SO_4 is a strong oxidizing agent. Instead of producing H2H_2 gas, it reacts with zinc to produce sulphur dioxide (SO2SO_2) gas and water.

Explanation:

The reaction follows: Zn+2H2SO4 (conc.)ZnSO4+SO2+2H2OZn + 2H_2SO_4 \text{ (conc.)} \rightarrow ZnSO_4 + SO_2 + 2H_2O. Since the goal is to produce H2H_2, the oxidizing nature of the concentrated acid interferes with the result.

Problem 2:

What observation is made when H2H_2 gas is passed over heated lead(II) oxide (PbOPbO)?

Solution:

The yellow-colored lead(II) oxide (PbOPbO) is reduced to a greyish-white metallic lead (PbPb), and droplets of water are seen at the cooler parts of the tube.

Explanation:

This is a redox reaction where hydrogen acts as the reducing agent: PbO+H2Pb+H2OPbO + H_2 \rightarrow Pb + H_2O. The PbOPbO loses oxygen (reduction) and H2H_2 gains oxygen (oxidation).

Problem 3:

Identify the catalyst used in the Haber process and the hydrogenation of oils.

Solution:

In the Haber process, Finely divided Iron (FeFe) is the catalyst with Molybdenum (MoMo) as a promoter. In the hydrogenation of oils, Nickel (NiNi) is used as the catalyst.

Explanation:

Catalysts are substances that increase the rate of a chemical reaction without being consumed. FeFe helps in the synthesis of NH3NH_3 and NiNi helps in converting liquid oils to solid fats.