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Chemical Changes and Reactions - Conditions for Chemical Changes

Grade 7ICSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

A chemical change is a permanent change in which the chemical composition of a substance is altered and one or more new substances are formed. For example: 2Mg+O22MgO2Mg + O_2 \rightarrow 2MgO.

Close Contact: Some chemical reactions occur only when the reactants are brought into close contact in their solid state, such as iodine and phosphorus reacting spontaneously.

Solution Form: Certain substances react only when they are in a solution state (aqueous). For example, AgNO3(aq)AgNO_3(aq) reacts with NaCl(aq)NaCl(aq) to form a precipitate of AgClAgCl.

Heat: Many reactions require the supply of heat energy to initiate. These are often thermal decomposition reactions, such as 2KClO3Δ2KCl+3O22KClO_3 \xrightarrow{\Delta} 2KCl + 3O_2.

Light (Photochemical Reactions): Some reactions take place only in the presence of light. A primary example is photosynthesis: 6CO2+6H2OlightC6H12O6+6O26CO_2 + 6H_2O \xrightarrow{\text{light}} C_6H_{12}O_6 + 6O_2.

Electricity (Electrochemical Reactions): Certain compounds decompose when an electric current is passed through them in a liquid or molten state, such as the electrolysis of water: 2H2Oelectricity2H2+O22H_2O \xrightarrow{\text{electricity}} 2H_2 + O_2.

Pressure: High pressure is required for certain gaseous reactions, such as the synthesis of ammonia where N2N_2 and H2H_2 react at high pressure.

Catalysts: Substances that increase or decrease the rate of a chemical reaction without undergoing any permanent chemical change themselves. For example, MnO2MnO_2 acts as a catalyst in the decomposition of H2O2H_2O_2.

📐Formulae

2H2O2MnO22H2O+O22H_2O_2 \xrightarrow{MnO_2} 2H_2O + O_2 \uparrow

N2+3H2200900 atmFe,Mo2NH3N_2 + 3H_2 \xrightleftharpoons[200-900 \text{ atm}]{Fe, Mo} 2NH_3

CaCO3ΔCaO+CO2CaCO_3 \xrightarrow{\Delta} CaO + CO_2 \uparrow

2AgClsunlight2Ag+Cl22AgCl \xrightarrow{\text{sunlight}} 2Ag + Cl_2 \uparrow

💡Examples

Problem 1:

What happens when NaClNaCl and AgNO3AgNO_3 solutions are mixed? Name the condition required.

Solution:

NaCl(aq)+AgNO3(aq)AgCl(s)+NaNO3(aq)NaCl(aq) + AgNO_3(aq) \rightarrow AgCl(s) \downarrow + NaNO_3(aq)

Explanation:

This is a precipitation reaction. The condition required is that the reactants must be in their 'Solution state' (Aqueous) for the ions to move freely and react.

Problem 2:

Identify the catalyst used in the manufacture of ammonia by Haber's process and the necessary pressure condition.

Solution:

Catalyst: Iron (FeFe); Promoter: Molybdenum (MoMo); Pressure: Above 200200 atmospheres.

Explanation:

In Haber's process (N2+3H22NH3N_2 + 3H_2 \rightleftharpoons 2NH_3), the reaction is reversible and requires high pressure and a catalyst to increase the yield and speed of ammonia production.

Problem 3:

Explain why silver nitrate is stored in dark-colored bottles.

Solution:

2AgNO3light2Ag+2NO2+O22AgNO_3 \xrightarrow{\text{light}} 2Ag + 2NO_2 + O_2

Explanation:

Silver nitrate is photosensitive. In the presence of light, it undergoes a photochemical decomposition. To prevent this chemical change, it is stored in dark bottles that block light.