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Properties and Changes of Materials - Irreversible changes (burning, rusting, mixing acid and bicarbonate of soda)

Grade 5Cambridge (IGCSE)

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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An irreversible change is a permanent transformation that cannot be easily undone to get the original materials back. During these changes, new substances are always formed.

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Burning (Combustion) is an irreversible change where a fuel reacts with oxygen (O2O_2) from the air to produce heat, light, ash, and gases like carbon dioxide (CO2CO_2) and water vapor (H2OH_2O).

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Rusting is a slow irreversible change that occurs when iron (FeFe) reacts with both oxygen (O2O_2) and water (H2OH_2O). The new substance formed is called iron oxide (Fe2O3Fe_2O_3), which is a reddish-brown flaky solid.

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Mixing an acid (like vinegar) with bicarbonate of soda (NaHCO3NaHCO_3) creates a chemical reaction that produces salt, water (H2OH_2O), and carbon dioxide (CO2CO_2) gas. The fizzing or bubbling is a sign that a new gas is being formed.

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Signs of an irreversible change include: a change in color, the production of a gas (bubbles/fizzing), the release of heat or light, and the formation of a completely new material.

📐Formulae

Fuel+O2→CO2+H2O+Ash+Heat/Light\text{Fuel} + O_2 \rightarrow CO_2 + H_2O + \text{Ash} + \text{Heat/Light}

Iron+Oxygen+Water→Hydrated Iron(III) Oxide (Rust)\text{Iron} + \text{Oxygen} + \text{Water} \rightarrow \text{Hydrated Iron(III) Oxide (Rust)}

NaHCO3+CH3COOH→CH3COONa+H2O+CO2NaHCO_3 + CH_3COOH \rightarrow CH_3COONa + H_2O + CO_2

4Fe+3O2+6H2O→4Fe(OH)34Fe + 3O_2 + 6H_2O \rightarrow 4Fe(OH)_3

💡Examples

Problem 1:

When you burn a piece of wood, it turns into grey ash. Is this a reversible or irreversible change? Explain using the products formed.

Solution:

This is an irreversible change.

Explanation:

Burning wood is a chemical reaction where the wood reacts with oxygen (O2O_2) to create new substances: ash, carbon dioxide (CO2CO_2), and water vapor (H2OH_2O). You cannot turn the ash and smoke back into the original piece of wood.

Problem 2:

A student places an iron nail in a jar of water. After a week, the nail is covered in a brownish-orange crust. Identify the process and the chemical name of the new substance.

Solution:

The process is rusting, and the new substance is iron oxide (Fe2O3Fe_2O_3).

Explanation:

The iron (FeFe) in the nail reacted with the oxygen (O2O_2) dissolved in the water (H2OH_2O) to form a new material. This is irreversible because the rust cannot be turned back into shiny iron through simple physical means.

Problem 3:

What happens to the temperature and state of matter when vinegar is mixed with bicarbonate of soda (NaHCO3NaHCO_3)?

Solution:

The mixture fizzes (releases gas) and the temperature usually drops slightly.

Explanation:

When the acid (vinegar) and the base (bicarbonate of soda) react, they produce carbon dioxide (CO2CO_2) gas, which causes the bubbling. This production of gas and the formation of new substances (sodium acetate and water) indicate an irreversible chemical change.