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Chemistry - Organic Chemistry

Grade 10IGCSE

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Homologous Series: A family of organic compounds with the same functional group and general formula. Each member differs by a CH2CH_2 unit (e.g., Alkanes, Alkenes, Alcohols).

Hydrocarbons: Compounds containing only carbon and hydrogen atoms. Alkanes (CnH2n+2C_nH_{2n+2}) are saturated (single bonds only), while Alkenes (CnH2nC_nH_{2n}) are unsaturated (contain at least one C=CC=C double bond).

Fractional Distillation: The process of separating crude oil into useful fractions (like petrol, diesel, and bitumen) based on their boiling points.

Cracking: A thermal decomposition reaction where long-chain alkanes are broken down into smaller, more useful molecules like shorter alkanes and alkenes (e.g., C10H22C8H18+C2H4C_{10}H_{22} \rightarrow C_8H_{18} + C_2H_4).

Functional Groups: Specific atoms or groups of atoms that determine the chemical properties of a molecule, such as the hydroxyl group (OH-OH) in alcohols and the carboxyl group (COOH-COOH) in carboxylic acids.

Addition Reactions: Characteristic of alkenes where the C=CC=C double bond breaks to bond with other atoms, such as in Bromination (+Br2+ Br_2) or Hydration (+H2O+ H_2O).

Polymerization: Addition polymerization involves monomers with C=CC=C bonds joining to form long chains (e.g., Ethene becoming Poly(ethene)). Condensation polymerization involves monomers with two functional groups reacting to form a polymer and a small molecule like H2OH_2O (e.g., Nylon or Terylene).

📐Formulae

CnH2n+2C_nH_{2n+2}

CnH2nC_nH_{2n}

CnH2n+1OHC_nH_{2n+1}OH

CnH2n+1COOHC_nH_{2n+1}COOH

CH4+2O2CO2+2H2OCH_4 + 2O_2 \rightarrow CO_2 + 2H_2O

C2H4+Br2C2H4Br2C_2H_4 + Br_2 \rightarrow C_2H_4Br_2

C2H4+H2OH3PO4,300CC2H5OHC_2H_4 + H_2O \xrightarrow{H_3PO_4, 300^\circ C} C_2H_5OH

💡Examples

Problem 1:

Calculate the molecular formula of an alkane that contains 1212 carbon atoms.

Solution:

The molecular formula is C12H26C_{12}H_{26}.

Explanation:

Using the general formula for alkanes, CnH2n+2C_nH_{2n+2}, where n=12n = 12: H=2(12)+2=24+2=26H = 2(12) + 2 = 24 + 2 = 26. Therefore, the formula is C12H26C_{12}H_{26}.

Problem 2:

Describe a chemical test to distinguish between Propane (C3H8C_3H_8) and Propene (C3H6C_3H_6).

Solution:

Add aqueous bromine (Br2(aq)Br_2(aq)) to both samples.

Explanation:

Propene (an alkene) will undergo an addition reaction and decolorize the bromine water from orange/brown to colorless. Propane (an alkane) will not react, and the solution will remain orange.

Problem 3:

Write the structural formula and identify the product formed when Ethanoic Acid (CH3COOHCH_3COOH) reacts with Ethanol (C2H5OHC_2H_5OH) in the presence of an acid catalyst.

Solution:

Product: Ethyl Ethanoate (CH3COOC2H5CH_3COOC_2H_5) and Water (H2OH_2O).

Explanation:

This is an esterification reaction. The OH-OH from the carboxylic acid and the H-H from the alcohol's hydroxyl group combine to form H2OH_2O, while the remaining fragments join to form an ester bond (COO-COO-).