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Metals - Reactivity series

Grade 12IGCSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

The reactivity series is an arrangement of metals in order of their decreasing reactivity, determined by their tendency to lose electrons and form positive ions (MMn++neM \rightarrow M^{n+} + ne^-).

The standard order (from most to least reactive) is: Potassium (KK), Sodium (NaNa), Calcium (CaCa), Magnesium (MgMg), Aluminium (AlAl), Carbon (CC), Zinc (ZnZn), Iron (FeFe), Hydrogen (HH), Copper (CuCu), Silver (AgAg), and Gold (AuAu).

Metals above hydrogen in the series react with dilute acids (such as HClHCl or H2SO4H_2SO_4) to produce a metal salt and hydrogen gas (H2H_2).

Highly reactive metals (KK, NaNa, CaCa) react vigorously with cold water to produce a metal hydroxide (MOHMOH or M(OH)2M(OH)_2) and hydrogen gas (H2H_2).

Metals like Magnesium (MgMg) react slowly with cold water but vigorously with steam to produce a metal oxide (MgOMgO) and H2H_2.

In a displacement reaction, a more reactive metal will displace a less reactive metal from its aqueous salt solution, e.g., Mg(s)+CuSO4(aq)MgSO4(aq)+Cu(s)Mg(s) + CuSO_4(aq) \rightarrow MgSO_4(aq) + Cu(s).

The method of extraction depends on reactivity: metals above Carbon are extracted via electrolysis of molten ores, while metals below Carbon are extracted by reduction using Carbon or Carbon Monoxide (COCO).

Thermal stability of compounds increases with the reactivity of the metal. For example, carbonates of reactive metals like KK and NaNa do not decompose upon heating, while CuCO3CuCO_3 decomposes easily into CuOCuO and CO2CO_2.

📐Formulae

Metal+WaterMetal Hydroxide+HydrogenMetal + Water \rightarrow Metal\ Hydroxide + Hydrogen

Metal+AcidSalt+HydrogenMetal + Acid \rightarrow Salt + Hydrogen

Fe2O3(s)+3CO(g)2Fe(l)+3CO2(g)Fe_2O_3(s) + 3CO(g) \rightarrow 2Fe(l) + 3CO_2(g)

2PbO(s)+C(s)2Pb(s)+CO2(g)2PbO(s) + C(s) \rightarrow 2Pb(s) + CO_2(g)

CuCO3(s)ΔCuO(s)+CO2(g)CuCO_3(s) \xrightarrow{\Delta} CuO(s) + CO_2(g)

💡Examples

Problem 1:

Predict the observation and write the balanced chemical equation when Zinc (ZnZn) granules are added to a solution of Copper(II) Sulfate (CuSO4CuSO_4).

Solution:

Zn(s)+CuSO4(aq)ZnSO4(aq)+Cu(s)Zn(s) + CuSO_4(aq) \rightarrow ZnSO_4(aq) + Cu(s) Observations: The blue color of the CuSO4CuSO_4 solution fades/becomes colorless, and a reddish-brown solid (CuCu) is deposited on the Zinc.

Explanation:

Zinc is more reactive than Copper because it is higher in the reactivity series. Therefore, Zinc atoms lose electrons more readily than Copper, displacing Cu2+Cu^{2+} ions from the solution to form Zn2+Zn^{2+} ions.

Problem 2:

Explain why Aluminium (AlAl) is extracted using electrolysis rather than reduction with Carbon, despite Carbon being cheaper.

Solution:

Aluminium is more reactive than Carbon. In the reactivity series, AlAl is placed above CC.

Explanation:

Because Aluminium has a higher affinity for oxygen than Carbon does, Carbon is not a strong enough reducing agent to remove oxygen from Aluminium Oxide (Al2O3Al_2O_3). Therefore, large amounts of electrical energy are required to decompose the ore via electrolysis.

Reactivity series - Revision Notes & Key Formulas | IGCSE Grade 12 Chemistry