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Metals - Reactivity series

Grade 12A LevelChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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The reactivity series is an arrangement of metals in order of their decreasing reactivity, determined by their tendency to lose electrons and form positive ions (M→Mn++ne−M \rightarrow M^{n+} + ne^-).

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The standard order (from most to least reactive) is: Potassium (KK), Sodium (NaNa), Calcium (CaCa), Magnesium (MgMg), Aluminium (AlAl), Carbon (CC), Zinc (ZnZn), Iron (FeFe), Hydrogen (HH), Copper (CuCu), Silver (AgAg), and Gold (AuAu).

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Metals above hydrogen in the series react with dilute acids (such as HClHCl or H2SO4H_2SO_4) to produce a metal salt and hydrogen gas (H2H_2).

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Highly reactive metals (KK, NaNa, CaCa) react vigorously with cold water to produce a metal hydroxide (MOHMOH or M(OH)2M(OH)_2) and hydrogen gas (H2H_2).

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Metals like Magnesium (MgMg) react slowly with cold water but vigorously with steam to produce a metal oxide (MgOMgO) and H2H_2.

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In a displacement reaction, a more reactive metal will displace a less reactive metal from its aqueous salt solution, e.g., Mg(s)+CuSO4(aq)→MgSO4(aq)+Cu(s)Mg(s) + CuSO_4(aq) \rightarrow MgSO_4(aq) + Cu(s).

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The method of extraction depends on reactivity: metals above Carbon are extracted via electrolysis of molten ores, while metals below Carbon are extracted by reduction using Carbon or Carbon Monoxide (COCO).

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Thermal stability of compounds increases with the reactivity of the metal. For example, carbonates of reactive metals like KK and NaNa do not decompose upon heating, while CuCO3CuCO_3 decomposes easily into CuOCuO and CO2CO_2.

📐Formulae

Metal+Water→Metal Hydroxide+HydrogenMetal + Water \rightarrow Metal\ Hydroxide + Hydrogen

Metal+Acid→Salt+HydrogenMetal + Acid \rightarrow Salt + Hydrogen

Fe2O3(s)+3CO(g)→2Fe(l)+3CO2(g)Fe_2O_3(s) + 3CO(g) \rightarrow 2Fe(l) + 3CO_2(g)

2PbO(s)+C(s)→2Pb(s)+CO2(g)2PbO(s) + C(s) \rightarrow 2Pb(s) + CO_2(g)

CuCO3(s)→ΔCuO(s)+CO2(g)CuCO_3(s) \xrightarrow{\Delta} CuO(s) + CO_2(g)

💡Examples

Problem 1:

Predict the observation and write the balanced chemical equation when Zinc (ZnZn) granules are added to a solution of Copper(II) Sulfate (CuSO4CuSO_4).

Solution:

Zn(s)+CuSO4(aq)→ZnSO4(aq)+Cu(s)Zn(s) + CuSO_4(aq) \rightarrow ZnSO_4(aq) + Cu(s) Observations: The blue color of the CuSO4CuSO_4 solution fades/becomes colorless, and a reddish-brown solid (CuCu) is deposited on the Zinc.

Explanation:

Zinc is more reactive than Copper because it is higher in the reactivity series. Therefore, Zinc atoms lose electrons more readily than Copper, displacing Cu2+Cu^{2+} ions from the solution to form Zn2+Zn^{2+} ions.

Problem 2:

Explain why Aluminium (AlAl) is extracted using electrolysis rather than reduction with Carbon, despite Carbon being cheaper.

Solution:

Aluminium is more reactive than Carbon. In the reactivity series, AlAl is placed above CC.

Explanation:

Because Aluminium has a higher affinity for oxygen than Carbon does, Carbon is not a strong enough reducing agent to remove oxygen from Aluminium Oxide (Al2O3Al_2O_3). Therefore, large amounts of electrical energy are required to decompose the ore via electrolysis.