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Metals - Properties of metals

Grade 12IGCSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

Metallic Bonding: Defined as the electrostatic attraction between a lattice of positive metal ions (Mn+M^{n+}) and a 'sea' of delocalized electrons.

Electrical Conductivity: Metals conduct electricity because the delocalized electrons are free to move throughout the giant metallic lattice when a voltage is applied.

Malleability and Ductility: Metals can be hammered into shapes or drawn into wires because the layers of positive ions can slide over each other without breaking the metallic bond, as the sea of electrons acts as a 'glue'.

Thermal Conductivity: Heat energy is transferred through metals by the vibration of closely packed ions and the kinetic energy carried by rapidly moving delocalized electrons.

Alloys: An alloy is a mixture of a metal with other elements. Alloys are harder than pure metals because atoms of different sizes disrupt the regular arrangement of the lattice, making it difficult for layers to slide over one another.

Reactivity Series: Metals are arranged in order of their ability to lose electrons and form positive ions. Metals higher in the series, such as KK and NaNa, react more vigorously with water and acids than those lower down, like CuCu or AgAg.

Chemical Properties: Metals generally react with oxygen to form basic oxides (e.g., MgOMgO), and with dilute acids to produce a salt and hydrogen gas (H2H_2).

📐Formulae

Metal+WaterMetal Hydroxide+HydrogenMetal + Water \rightarrow Metal\ Hydroxide + Hydrogen

Metal+AcidSalt+HydrogenMetal + Acid \rightarrow Salt + Hydrogen

2Mg(s)+O2(g)2MgO(s)2Mg(s) + O_2(g) \rightarrow 2MgO(s)

Zn(s)+H2SO4(aq)ZnSO4(aq)+H2(g)Zn(s) + H_2SO_4(aq) \rightarrow ZnSO_4(aq) + H_2(g)

Fe2O3(s)+2Al(s)Al2O3(s)+2Fe(l)Fe_2O_3(s) + 2Al(s) \rightarrow Al_2O_3(s) + 2Fe(l)

💡Examples

Problem 1:

Explain why Magnesium (MgMg) has a higher melting point than Sodium (NaNa).

Solution:

MgMg has a higher charge density than NaNa. MgMg forms Mg2+Mg^{2+} ions and contributes two delocalized electrons per atom, whereas NaNa forms Na+Na^{+} ions and contributes only one.

Explanation:

The electrostatic attraction between the Mg2+Mg^{2+} ions and the larger number of delocalized electrons is stronger than in Na+Na^{+}, requiring more thermal energy to break the metallic bonds.

Problem 2:

Write the ionic equation for the displacement reaction between Zinc (ZnZn) and Copper(II) Sulfate (CuSO4CuSO_4).

Solution:

Zn(s)+Cu2+(aq)Zn2+(aq)+Cu(s)Zn(s) + Cu^{2+}(aq) \rightarrow Zn^{2+}(aq) + Cu(s)

Explanation:

Zinc is more reactive than copper; it loses electrons (oxidation) more readily to become Zn2+Zn^{2+}, while Cu2+Cu^{2+} ions gain those electrons (reduction) to form solid copper metal.

Problem 3:

Calculate the mass of Hydrogen gas produced when 4.8 g4.8\ g of Magnesium reacts completely with excess HClHCl. (Atomic mass: Mg=24Mg = 24)

Solution:

Moles of Mg=4.824=0.2 molMg = \frac{4.8}{24} = 0.2\ mol. From the equation Mg+2HClMgCl2+H2Mg + 2HCl \rightarrow MgCl_2 + H_2, the molar ratio is 1:11:1. Moles of H2=0.2 molH_2 = 0.2\ mol. Mass of H2=0.2×2=0.4 gH_2 = 0.2 \times 2 = 0.4\ g.

Explanation:

Using the stoichiometry of the reaction, the number of moles of metal determines the yield of hydrogen gas based on its valence.

Properties of metals - Revision Notes & Key Formulas | IGCSE Grade 12 Chemistry