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Chemistry of the Environment - Air quality and climate

Grade 12A LevelChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

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The atmosphere is a mixture of gases: approximately 78%78\% Nitrogen (N2N_2), 21%21\% Oxygen (O2O_2), 0.9%0.9\% Argon (ArAr), and 0.04%0.04\% Carbon dioxide (CO2CO_2).

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Pollutants such as Carbon monoxide (COCO) are produced by the incomplete combustion of carbon-containing fuels, while Sulfur dioxide (SO2SO_2) is produced from the combustion of fossil fuels containing sulfur compounds.

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Oxides of nitrogen (NOxNO_x) are formed in car engines where high temperatures and pressures cause the N2N_2 and O2O_2 from the air to react.

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Particulates, such as unburnt carbon (soot), are produced by incomplete combustion and can cause respiratory problems and global dimming.

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The greenhouse effect is caused by gases like Carbon dioxide (CO2CO_2) and Methane (CH4CH_4) absorbing thermal energy (infrared radiation) and re-emitting it back towards Earth, leading to global warming.

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Ocean acidification occurs when increased levels of CO2CO_2 dissolve in seawater to form carbonic acid (H2CO3H_2CO_3), which lowers the pHpH and affects marine life like coral reefs.

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Catalytic converters in vehicles reduce the emission of toxic gases by providing a surface for reactions that convert NOxNO_x and COCO into N2N_2 and CO2CO_2.

📐Formulae

S+O2→SO2S + O_2 \rightarrow SO_2

2CO+O2→2CO22CO + O_2 \rightarrow 2CO_2

N2+O2→2NON_2 + O_2 \rightarrow 2NO

2NO+2CO→N2+2CO22NO + 2CO \rightarrow N_2 + 2CO_2

2NO2→N2+2O22NO_2 \rightarrow N_2 + 2O_2

CO2+H2O⇌H2CO3CO_2 + H_2O \rightleftharpoons H_2CO_3

6CO2+6H2O→lightC6H12O6+6O26CO_2 + 6H_2O \xrightarrow{\text{light}} C_6H_{12}O_6 + 6O_2

💡Examples

Problem 1:

Calculate the volume of Oxygen (O2O_2) present in a 500 dm3500\text{ dm}^3 sample of clean, dry air.

Solution:

VO2=500 dm3×0.21=105 dm3V_{O_2} = 500\text{ dm}^3 \times 0.21 = 105\text{ dm}^3

Explanation:

Since clean air contains approximately 21%21\% oxygen by volume, we multiply the total volume by 0.210.21.

Problem 2:

Write the chemical equation for the formation of acid rain from sulfur dioxide reacting with water and oxygen in the atmosphere.

Solution:

2SO2+O2+2H2O→2H2SO42SO_2 + O_2 + 2H_2O \rightarrow 2H_2SO_4

Explanation:

Sulfur dioxide (SO2SO_2) is oxidized in the atmosphere and reacts with water vapor to form sulfuric acid (H2SO4H_2SO_4), a major component of acid rain.

Problem 3:

Explain how the reaction in a catalytic converter reduces the environmental impact of car exhaust.

Solution:

2NO(g)+2CO(g)→N2(g)+2CO2(g)2NO(g) + 2CO(g) \rightarrow N_2(g) + 2CO_2(g)

Explanation:

The catalytic converter facilitates a redox reaction where Nitrogen monoxide (NONO) is reduced to harmless Nitrogen gas (N2N_2) and Carbon monoxide (COCO) is oxidized to Carbon dioxide (CO2CO_2).