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Chemistry of the Environment - Air quality and climate

Grade 12IGCSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

The atmosphere is a mixture of gases: approximately 78%78\% Nitrogen (N2N_2), 21%21\% Oxygen (O2O_2), 0.9%0.9\% Argon (ArAr), and 0.04%0.04\% Carbon dioxide (CO2CO_2).

Pollutants such as Carbon monoxide (COCO) are produced by the incomplete combustion of carbon-containing fuels, while Sulfur dioxide (SO2SO_2) is produced from the combustion of fossil fuels containing sulfur compounds.

Oxides of nitrogen (NOxNO_x) are formed in car engines where high temperatures and pressures cause the N2N_2 and O2O_2 from the air to react.

Particulates, such as unburnt carbon (soot), are produced by incomplete combustion and can cause respiratory problems and global dimming.

The greenhouse effect is caused by gases like Carbon dioxide (CO2CO_2) and Methane (CH4CH_4) absorbing thermal energy (infrared radiation) and re-emitting it back towards Earth, leading to global warming.

Ocean acidification occurs when increased levels of CO2CO_2 dissolve in seawater to form carbonic acid (H2CO3H_2CO_3), which lowers the pHpH and affects marine life like coral reefs.

Catalytic converters in vehicles reduce the emission of toxic gases by providing a surface for reactions that convert NOxNO_x and COCO into N2N_2 and CO2CO_2.

📐Formulae

S+O2SO2S + O_2 \rightarrow SO_2

2CO+O22CO22CO + O_2 \rightarrow 2CO_2

N2+O22NON_2 + O_2 \rightarrow 2NO

2NO+2CON2+2CO22NO + 2CO \rightarrow N_2 + 2CO_2

2NO2N2+2O22NO_2 \rightarrow N_2 + 2O_2

CO2+H2OH2CO3CO_2 + H_2O \rightleftharpoons H_2CO_3

6CO2+6H2OlightC6H12O6+6O26CO_2 + 6H_2O \xrightarrow{\text{light}} C_6H_{12}O_6 + 6O_2

💡Examples

Problem 1:

Calculate the volume of Oxygen (O2O_2) present in a 500 dm3500\text{ dm}^3 sample of clean, dry air.

Solution:

VO2=500 dm3×0.21=105 dm3V_{O_2} = 500\text{ dm}^3 \times 0.21 = 105\text{ dm}^3

Explanation:

Since clean air contains approximately 21%21\% oxygen by volume, we multiply the total volume by 0.210.21.

Problem 2:

Write the chemical equation for the formation of acid rain from sulfur dioxide reacting with water and oxygen in the atmosphere.

Solution:

2SO2+O2+2H2O2H2SO42SO_2 + O_2 + 2H_2O \rightarrow 2H_2SO_4

Explanation:

Sulfur dioxide (SO2SO_2) is oxidized in the atmosphere and reacts with water vapor to form sulfuric acid (H2SO4H_2SO_4), a major component of acid rain.

Problem 3:

Explain how the reaction in a catalytic converter reduces the environmental impact of car exhaust.

Solution:

2NO(g)+2CO(g)N2(g)+2CO2(g)2NO(g) + 2CO(g) \rightarrow N_2(g) + 2CO_2(g)

Explanation:

The catalytic converter facilitates a redox reaction where Nitrogen monoxide (NONO) is reduced to harmless Nitrogen gas (N2N_2) and Carbon monoxide (COCO) is oxidized to Carbon dioxide (CO2CO_2).

Air quality and climate - Revision Notes & Key Formulas | IGCSE Grade 12 Chemistry