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Acids, Bases and Salts - Types of oxides

Grade 12IGCSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

πŸ”‘Concepts

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Oxides are binary compounds of oxygen with another element. They are classified based on their acid-base behavior into four types: acidic, basic, amphoteric, and neutral.

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Acidic Oxides: Formed by non-metals (e.g., CO2CO_2, SO2SO_2, P4O10P_4O_{10}). These oxides react with bases to form a salt and water, and most dissolve in water to produce acidic solutions containing H+H^+ ions.

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Basic Oxides: Formed by metals (e.g., CaOCaO, CuOCuO, MgOMgO). These oxides react with acids to form a salt and water. Soluble basic oxides are called alkalis and dissolve in water to produce OHβˆ’OH^- ions.

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Amphoteric Oxides: Metallic oxides that exhibit both acidic and basic properties (e.g., Al2O3Al_2O_3, ZnOZnO, PbOPbO). They can react with both strong acids and strong bases to produce salt and water.

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Neutral Oxides: Oxides that do not show any acidic or basic properties. They do not react with acids or bases. Common examples include COCO, NONO, N2ON_2O, and H2OH_2O.

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Across a period in the Periodic Table, the nature of oxides changes from Basic β†’\rightarrow Amphoteric β†’\rightarrow Acidic.

πŸ“Formulae

Metal Oxide+Acid→Salt+WaterMetal\ Oxide + Acid \rightarrow Salt + Water

Nonβˆ’metalΒ Oxide+Baseβ†’Salt+WaterNon-metal\ Oxide + Base \rightarrow Salt + Water

CO2(g)+H2O(l)β‡ŒH2CO3(aq)CO_2(g) + H_2O(l) \rightleftharpoons H_2CO_3(aq) (Acidic oxide in water)

Al2O3(s)+6HCl(aq)β†’2AlCl3(aq)+3H2O(l)Al_2O_3(s) + 6HCl(aq) \rightarrow 2AlCl_3(aq) + 3H_2O(l) (Amphoteric oxide as a base)

Al2O3(s)+2NaOH(aq)+3H2O(l)β†’2Na[Al(OH)4](aq)Al_2O_3(s) + 2NaOH(aq) + 3H_2O(l) \rightarrow 2Na[Al(OH)_4](aq) (Amphoteric oxide as an acid)

πŸ’‘Examples

Problem 1:

Identify the type of oxide and write the balanced chemical equation for the reaction between MgOMgO and H2SO4H_2SO_4.

Solution:

MgOMgO is a Basic Oxide. Equation: MgO(s)+H2SO4(aq)β†’MgSO4(aq)+H2O(l)MgO(s) + H_2SO_4(aq) \rightarrow MgSO_4(aq) + H_2O(l)

Explanation:

MgOMgO is a metal oxide that reacts with a strong acid (H2SO4H_2SO_4) to produce the salt magnesium sulfate and water, confirming its basic nature.

Problem 2:

Explain why ZnOZnO is classified as an amphoteric oxide using its reaction with HClHCl and NaOHNaOH.

Solution:

ZnOZnO reacts with HClHCl: ZnO+2HCl→ZnCl2+H2OZnO + 2HCl \rightarrow ZnCl_2 + H_2O ZnOZnO reacts with NaOHNaOH: ZnO+2NaOH+H2O→Na2[Zn(OH)4]ZnO + 2NaOH + H_2O \rightarrow Na_2[Zn(OH)_4]

Explanation:

Because ZnOZnO reacts with both a strong acid (HClHCl) and a strong base (NaOHNaOH) to produce a salt and water, it is defined as amphoteric.

Problem 3:

Which of the following oxides is neutral: SO3SO_3, CaOCaO, COCO, or Al_2_O_3?

Solution:

The neutral oxide is COCO.

Explanation:

SO3SO_3 is acidic, CaOCaO is basic, and Al2O3Al_2O_3 is amphoteric. COCO (carbon monoxide) does not react with acids or bases, making it neutral.

Types of oxides - Revision Notes & Key Formulas | IGCSE Grade 12 Chemistry