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States of Matter - States of matter and changes of state

Grade 11IGCSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

The Kinetic Particle Theory states that all matter is made of tiny particles (atoms, molecules, or ions) that are in constant, random motion.

In a Solid, particles are packed closely together in a regular lattice arrangement. They vibrate about fixed positions and have strong intermolecular forces of attraction.

In a Liquid, particles are close together but arranged randomly. They can move and slide past each other, allowing liquids to flow and take the shape of their container.

In a Gas, particles are far apart and move rapidly and randomly in all directions. Intermolecular forces are negligible, and gases are easily compressed.

Melting (SLS \rightarrow L) and Boiling (LGL \rightarrow G) are endothermic processes where energy is absorbed to overcome forces of attraction between particles.

Freezing (LSL \rightarrow S) and Condensation (GLG \rightarrow L) are exothermic processes where energy is released as particles form stronger bonds/attractions.

During a change of state, the temperature remains constant (represented by a plateau on a heating/cooling curve) because the energy is used to break or form bonds rather than changing the average kinetic energy (EkE_k).

Diffusion is the net movement of particles from a region of higher concentration to a region of lower concentration due to their random motion. The rate of diffusion is inversely proportional to the relative molecular mass (MrM_r).

Brownian Motion provides evidence for the kinetic particle theory; it is the random jerky motion of visible particles (like pollen or smoke) caused by collisions with invisible, fast-moving air or water molecules.

📐Formulae

P1V1=P2V2P_1V_1 = P_2V_2

V1T1=V2T2\frac{V_1}{T_1} = \frac{V_2}{T_2}

PV=nRTPV = nRT

Rate of Diffusion1Mr\text{Rate of Diffusion} \propto \frac{1}{\sqrt{M_r}}

T(K)=T(C)+273T(K) = T(^{\circ}C) + 273

💡Examples

Problem 1:

Explain why the temperature of a beaker of H2OH_2O remains at 100C100^{\circ}C while it is boiling, even though heat is still being supplied.

Solution:

The temperature remains constant at 100C100^{\circ}C because the thermal energy being supplied is used to overcome the intermolecular forces of attraction between H2OH_2O molecules to convert them from the liquid phase to the gas phase.

Explanation:

In a heating curve, a horizontal line (plateau) indicates a state change. During this time, the average kinetic energy of the particles does not increase; instead, the potential energy increases as particles move further apart.

Problem 2:

In a diffusion experiment, a glass tube is set up with cotton wool soaked in concentrated Ammonia (NH3NH_3, Mr=17M_r = 17) at one end and concentrated Hydrochloric Acid (HClHCl, Mr=36.5M_r = 36.5) at the other. Where will the white cloud of Ammonium Chloride (NH4ClNH_4Cl) form?

Solution:

The white cloud of NH4ClNH_4Cl will form closer to the HClHCl end of the tube.

Explanation:

According to the kinetic theory, lighter particles diffuse faster than heavier particles. Since Mr(NH3)=17M_r(NH_3) = 17 and Mr(HCl)=36.5M_r(HCl) = 36.5, the NH3NH_3 molecules travel a greater distance in the same amount of time compared to the HClHCl molecules.

States of matter and changes of state Revision - Grade 11 Chemistry IGCSE