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Acids, Bases and Salts - Properties of acids and bases

Grade 11IGCSEChemistry

Review the key concepts, formulae, and examples before starting your quiz.

πŸ”‘Concepts

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Acids are defined as proton donors (H+H^+ ions) according to the BrΓΈnsted-Lowry theory. When dissolved in water, they produce hydrogen ions, H+(aq)H^+(aq).

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Bases are defined as proton acceptors. Soluble bases are called alkalis and produce hydroxide ions, OHβˆ’(aq)OH^-(aq), in aqueous solutions.

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The pHpH scale ranges from 00 to 1414. pH<7pH < 7 indicates an acidic solution, pH=7pH = 7 is neutral (e.g., pure water), and pH>7pH > 7 indicates an alkaline solution.

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Strong acids, such as HClHCl, H2SO4H_2SO_4, and HNO3HNO_3, dissociate completely in water. Weak acids, such as CH3COOHCH_3COOH (ethanoic acid), dissociate only partially.

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Common indicators: Litmus (red in acid, blue in base), Phenolphthalein (colorless in acid, pink in base), and Methyl orange (red in acid, yellow in base).

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Acids react with reactive metals to produce a salt and hydrogen gas: Acid+Metal→Salt+H2(g)Acid + Metal \rightarrow Salt + H_2(g).

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Acids react with carbonates to produce a salt, water, and carbon dioxide: Acid+Carbonate→Salt+H2O(l)+CO2(g)Acid + Carbonate \rightarrow Salt + H_2O(l) + CO_2(g).

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Neutralization occurs when an acid reacts with a base (or alkali) to form a salt and water: H+(aq)+OHβˆ’(aq)β†’H2O(l)H^+(aq) + OH^-(aq) \rightarrow H_2O(l).

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Amphoteric oxides, such as Al2O3Al_2O_3 and ZnOZnO, are oxides that can react with both acids and bases to form salts and water.

πŸ“Formulae

Acid+Metal→Salt+H2Acid + Metal \rightarrow Salt + H_2

Acid+Base→Salt+H2OAcid + Base \rightarrow Salt + H_2O

Acid+Carbonate→Salt+H2O+CO2Acid + Carbonate \rightarrow Salt + H_2O + CO_2

H+(aq)+OHβˆ’(aq)β†’H2O(l)H^+(aq) + OH^-(aq) \rightarrow H_2O(l)

pH=βˆ’log⁑10[H+]pH = -\log_{10}[H^+]

πŸ’‘Examples

Problem 1:

Write the balanced chemical equation for the reaction between dilute hydrochloric acid (HClHCl) and calcium carbonate (CaCO3CaCO_3).

Solution:

2HCl(aq)+CaCO3(s)β†’CaCl2(aq)+H2O(l)+CO2(g)2HCl(aq) + CaCO_3(s) \rightarrow CaCl_2(aq) + H_2O(l) + CO_2(g)

Explanation:

This is a typical acid-carbonate reaction. The products are the salt (calcium chloride), water, and carbon dioxide gas. Effervescence (bubbling) is observed due to the release of CO2CO_2.

Problem 2:

Calculate the mass of magnesium needed to react completely with 5050 cm3cm^3 of 2.02.0 mol/dm3mol/dm^3 sulfuric acid (H2SO4H_2SO_4). [Ar: Mg=24Mg = 24]

Solution:

  1. Moles of H2SO4=ConcentrationΓ—Volume=2.0Γ—501000=0.1H_2SO_4 = Concentration \times Volume = 2.0 \times \frac{50}{1000} = 0.1 molmol.
  2. Equation: Mg+H2SO4β†’MgSO4+H2Mg + H_2SO_4 \rightarrow MgSO_4 + H_2.
  3. Mole ratio of Mg:H2SO4Mg:H_2SO_4 is 1:11:1, so 0.10.1 molmol of MgMg is required.
  4. Mass of Mg=0.1Γ—24=2.4Mg = 0.1 \times 24 = 2.4 gg.

Explanation:

Using the balanced equation, we determine the stoichiometry (1:11:1) and convert the molar concentration of the acid into the mass of the metal.

Properties of acids and bases - Revision Notes & Key Formulas | IGCSE Grade 11 Chemistry