Review the key concepts, formulae, and examples before starting your quiz.
🔑Concepts
Bohr's model is based on the quantization of energy. He proposed that electrons revolve around the nucleus in specific circular paths called 'orbits' or 'stationary states' without radiating energy. These orbits are associated with a fixed amount of energy and are designated by the principal quantum number (or shells).
The angular momentum of an electron in a given orbit is quantized. An electron can revolve only in those orbits for which its angular momentum is an integral multiple of . This is expressed as , where is the mass, is the velocity, and is the radius of the orbit.
Energy is emitted or absorbed only when an electron jumps from one stationary state to another. Energy is absorbed () when jumping to a higher level () and emitted () when falling to a lower level ().
The energy difference between two levels is given by , where is Planck's constant () and is the frequency of the radiation.
Bohr's theory successfully explains the line spectrum of Hydrogen and Hydrogen-like species (ions with only one electron like , , and ).
📐Formulae
💡Examples
Problem 1:
Calculate the radius of the third orbit () of a ion.
Solution:
For , the atomic number . The formula for the radius is . Substituting the values:
Explanation:
The radius of a Bohr orbit is directly proportional to the square of the principal quantum number and inversely proportional to the atomic number .
Problem 2:
Calculate the energy of an electron in the second excited state of a Hydrogen atom.
Solution:
The second excited state corresponds to (since is the ground state and is the first excited state). For Hydrogen, . Using the formula :
Explanation:
Energy levels in a Hydrogen atom are negative, indicating that the electron is bound to the nucleus. As increases, the energy becomes less negative (higher energy).