Review the key concepts, formulae, and examples before starting your quiz.
🔑Concepts
A homologous series is a series of compounds with the same functional group and general formula. Members show a gradation in physical properties, such as boiling point, which increases with the number of carbon atoms due to increased London dispersion forces.
Functional groups are specific atoms or groups of atoms within a molecule that determine its chemical reactivity. Examples include the hydroxyl group () in alcohols and the carboxyl group () in carboxylic acids.
Structural isomers are compounds that have the same molecular formula but different structural arrangements of atoms (e.g., and ).
Saturated hydrocarbons (alkanes) contain only single bonds, while unsaturated hydrocarbons (alkenes, alkynes) contain double () or triple () carbon-carbon bonds.
Benzene () is an aromatic hydrocarbon. It exists as a planar hexagonal ring with delocalized electrons, which provides extra stability compared to theoretical cyclic alkenes.
Carbon atoms are classified as primary (), secondary (), or tertiary () based on how many other carbon atoms are bonded to the carbon atom attached to the functional group.
📐Formulae
💡Examples
Problem 1:
Provide the IUPAC name for the molecule: .
Solution:
-methylpentanal
Explanation:
The longest carbon chain containing the aldehyde functional group () has carbons (pentanal). Numbering begins at the carbonyl carbon. A methyl substituent is located on the carbon.
Problem 2:
Identify the number of structural isomers for the alkane .
Solution:
isomers
Explanation:
The two isomers are butane () and -methylpropane ().
Problem 3:
Classify as a primary, secondary, or tertiary alcohol.
Solution:
Tertiary () alcohol
Explanation:
The carbon atom bonded to the hydroxyl () group is bonded to three other carbon atoms (methyl groups), making it a tertiary carbon.