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Organisms and their Environment - Nutrient cycles (Carbon and Nitrogen)

Grade 12IGCSEBiology

Review the key concepts, formulae, and examples before starting your quiz.

🔑Concepts

The Carbon Cycle: The process by which carbon is exchanged between the atmosphere, biosphere, geosphere, and hydrosphere. Key processes include photosynthesis (6CO2+6H2OC6H12O6+6O26CO_2 + 6H_2O \rightarrow C_6H_{12}O_6 + 6O_2), respiration (C6H12O6+6O26CO2+6H2OC_6H_{12}O_6 + 6O_2 \rightarrow 6CO_2 + 6H_2O), decomposition, and combustion.

Carbon Sinks and Sources: Reservoirs that store carbon are sinks (e.g., oceans, forests as biomass, fossil fuels), while processes that release CO2CO_2 are sources (e.g., volcanic activity, burning fossil fuels).

The Nitrogen Cycle: Nitrogen is essential for synthesizing proteins and nucleic acids (DNA/RNA). Since atmospheric N2N_2 is inert due to a triple covalent bond, it must be 'fixed' into reactive forms like NH3NH_3 or NO3NO_3^-.

Nitrogen Fixation: Conversion of atmospheric N2N_2 gas into ammonia (NH3NH_3) or ammonium ions (NH4+NH_4^+) by nitrogen-fixing bacteria (e.g., Rhizobium in root nodules of legumes or Azotobacter in soil) or via lightning.

Nitrification: A two-step aerobic process where nitrifying bacteria convert ammonium (NH4+NH_4^+) into nitrites (NO2NO_2^-) (by Nitrosomonas) and then into nitrates (NO3NO_3^-) (by *Nitrobacter$).

Denitrification: The conversion of nitrates (NO3NO_3^-) back into nitrogen gas (N2N_2) by denitrifying bacteria (e.g., Thiobacillus denitrificans) typically occurring in anaerobic conditions like waterlogged soils.

Ammonification/Decomposition: Saprobionts break down organic nitrogen (from dead matter and urea) into ammonia (NH3NH_3), which then forms ammonium ions (NH4+NH_4^+) in the soil.

📐Formulae

6CO2+6H2Olight energyC6H12O6+6O26CO_2 + 6H_2O \xrightarrow{\text{light energy}} C_6H_{12}O_6 + 6O_2

C6H12O6+6O26CO2+6H2O+ATPC_6H_{12}O_6 + 6O_2 \rightarrow 6CO_2 + 6H_2O + \text{ATP}

N2+8H++8e2NH3+H2N_2 + 8H^+ + 8e^- \rightarrow 2NH_3 + H_2

2NH4++3O22NO2+4H++2H2O2NH_4^+ + 3O_2 \rightarrow 2NO_2^- + 4H^+ + 2H_2O

2NO2+O22NO32NO_2^- + O_2 \rightarrow 2NO_3^-

💡Examples

Problem 1:

Explain why waterlogged soils often lead to nitrogen deficiency in plants, specifically mentioning the ion NO3NO_3^-.

Solution:

In waterlogged soils, oxygen concentration is low, creating anaerobic conditions. This favors denitrifying bacteria, which convert nitrates (NO3NO_3^-) into gaseous nitrogen (N2N_2) through the process of denitrification. This reduces the availability of NO3NO_3^- ions for plant uptake via the roots.

Explanation:

Plants primarily absorb nitrogen in the form of NO3NO_3^- or NH4+NH_4^+. Denitrification removes the useful NO3NO_3^- from the soil ecosystem.

Problem 2:

Calculate the impact of burning 1000 kg1000\text{ kg} of methane (CH4CH_4) on atmospheric carbon, assuming complete combustion: CH4+2O2CO2+2H2OCH_4 + 2O_2 \rightarrow CO_2 + 2H_2O.

Solution:

Molar mass of CH416 g/molCH_4 \approx 16\text{ g/mol}. Molar mass of CO244 g/molCO_2 \approx 44\text{ g/mol}. For every 16 kg16\text{ kg} of CH4CH_4 burned, 44 kg44\text{ kg} of CO2CO_2 is produced. Therefore, 1000 kg1000\text{ kg} of CH4CH_4 produces 4416×1000=2750 kg\frac{44}{16} \times 1000 = 2750\text{ kg} of CO2CO_2.

Explanation:

Combustion shifts carbon from a long-term geospheric/biospheric store (fossil fuels/hydrocarbons) into the atmosphere as CO2CO_2, contributing to the greenhouse effect.